Wheel-Like Icosanuclear PeroxotitanateA Stable Water-Soluble Catalyst for Oxygen Transfer Reactions

Water-soluble wheel-like icosanuclear peroxotitanate K16[Ti20(μ-O)8(HO2)8(O2)12(R,R-tart)12]·52H2O (1) chelated by tartrate has been successfully isolated. As the largest peroxotitanate reported, {Ti20} features 20 (hydro)­peroxo groups with three kinds of coordination modes in μ-η1:η2, μ-η2:η2, and...

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Veröffentlicht in:	Inorganic chemistry 2018-11, Vol.57 (22), p.14116-14122
Hauptverfasser:	Jin, Wan-Ting, Yang, Fang, Deng, Lan, Chen, Mao-Long, Chen, Jun-Fei, Chen, Hong-Bin, Zhou, Zhao-Hui
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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