Exploring the Selective Demethylation of Aryl Methyl Ethers with a Pseudomonas Rieske Monooxygenase

Biocatalytic dealkylation of aryl methyl ethers is an attractive reaction for valorization of lignin components, as well as for deprotection of hydroxy functionalities in synthetic chemistry. We explored the demethylation of various aryl methyl ethers by using an oxidative demethylase from Pseudomon...

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Veröffentlicht in:	Chembiochem : a European journal of chemical biology 2019-01, Vol.20 (1), p.118-125
Hauptverfasser:	Lanfranchi, Elisa, Trajković, Miloš, Barta, Katalin, de Vries, Johannes G., Janssen, Dick B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids Aromatic compounds biocatalysis Carboxylic acids Cascade chemical reactions Catalysis Conversion Dealkylation Dehydrogenase Dehydrogenases Demethylation E coli Electron transfer Ethers Formaldehyde Formaldehyde dehydrogenase Formate dehydrogenase Lignin methoxy groups Monooxygenase NADH NADP Nicotinamide adenine dinucleotide O-demethylation Organic chemistry Phenols protein expression Proteins Protocatechuic acid Pseudomonas Regeneration Rieske monooxygenases Substrates Vanillic acid
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