Relative stereochemistries of the ether rings and sugar moieties in durinskiol A

Relative stereochemistries of the ether rings and sugar moieties in durinskiol A

Durinskiol A ( 1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conform...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Tetrahedron letters 2007-05, Vol.48 (19), p.3429-3432
Hauptverfasser: Kita, Masaki, Roy, Michael C., Siwu, Eric R.O., Noma, Isao, Takiguchi, Takahiro, Yamada, Kaoru, Koyama, Tomoyuki, Iwashita, Takeshi, Wakamiya, Atsushi, Uemura, Daisuke
Format: Artikel
Sprache:eng
Schlagworte:
Configuration determination
Durinskia
Glycosides
Molecular modeling
Natural products
Super-carbon-chain compounds
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 3432
container_issue 19
container_start_page 3429
container_title Tetrahedron letters
container_volume 48
creator Kita, Masaki
Roy, Michael C.
Siwu, Eric R.O.
Noma, Isao
Takiguchi, Takahiro
Yamada, Kaoru
Koyama, Tomoyuki
Iwashita, Takeshi
Wakamiya, Atsushi
Uemura, Daisuke
description Durinskiol A ( 1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.
doi_str_mv 10.1016/j.tetlet.2007.03.039
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_21245358</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0040403907004820</els_id><sourcerecordid>21245358</sourcerecordid><originalsourceid>FETCH-LOGICAL-c403t-578f5891014e10bcf4c88d4e66e2f8d2789db484b190cf34708206b95d74dff13</originalsourceid><addsrcrecordid>eNp9UE1LxDAQDaLguvoPPOTkreukTdv0IiyLX7CgiJ5Dm0x2s3YbTdIF_71Z6tlhmIGZ94Y3j5BrBgsGrLrdLSLGHuMiB6gXUKRsTsiMibrIilKwUzID4JDxND8nFyHsIEUlYEZe37Bvoz0gDRE9OrXFvQ3RWwzUGRq3SDEVT70dNoG2g6Zh3LSe7p3FeETZgeoxbcOndT1dXpIz0_YBr_76nHw83L-vnrL1y-PzarnOVFIRs7IWphRNks-RQacMV0JojlWFuRE6r0WjOy54xxpQpuA1iByqril1zbUxrJiTm-nul3ffI4Yok26Ffd8O6MYgc5bzMj2fgHwCKu9C8Gjkl7f71v9IBvJon9zJyT55tE9CkbJJtLuJhumJg0Uvg7I4KNTWo4pSO_v_gV_plHs4</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>21245358</pqid></control><display><type>article</type><title>Relative stereochemistries of the ether rings and sugar moieties in durinskiol A</title><source>Elsevier ScienceDirect Journals Complete</source><creator>Kita, Masaki ; Roy, Michael C. ; Siwu, Eric R.O. ; Noma, Isao ; Takiguchi, Takahiro ; Yamada, Kaoru ; Koyama, Tomoyuki ; Iwashita, Takeshi ; Wakamiya, Atsushi ; Uemura, Daisuke</creator><creatorcontrib>Kita, Masaki ; Roy, Michael C. ; Siwu, Eric R.O. ; Noma, Isao ; Takiguchi, Takahiro ; Yamada, Kaoru ; Koyama, Tomoyuki ; Iwashita, Takeshi ; Wakamiya, Atsushi ; Uemura, Daisuke</creatorcontrib><description>Durinskiol A ( 1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.</description><identifier>ISSN: 0040-4039</identifier><identifier>EISSN: 1873-3581</identifier><identifier>DOI: 10.1016/j.tetlet.2007.03.039</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Configuration determination ; Durinskia ; Glycosides ; Molecular modeling ; Natural products ; Super-carbon-chain compounds</subject><ispartof>Tetrahedron letters, 2007-05, Vol.48 (19), p.3429-3432</ispartof><rights>2007 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c403t-578f5891014e10bcf4c88d4e66e2f8d2789db484b190cf34708206b95d74dff13</citedby><cites>FETCH-LOGICAL-c403t-578f5891014e10bcf4c88d4e66e2f8d2789db484b190cf34708206b95d74dff13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.tetlet.2007.03.039$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Kita, Masaki</creatorcontrib><creatorcontrib>Roy, Michael C.</creatorcontrib><creatorcontrib>Siwu, Eric R.O.</creatorcontrib><creatorcontrib>Noma, Isao</creatorcontrib><creatorcontrib>Takiguchi, Takahiro</creatorcontrib><creatorcontrib>Yamada, Kaoru</creatorcontrib><creatorcontrib>Koyama, Tomoyuki</creatorcontrib><creatorcontrib>Iwashita, Takeshi</creatorcontrib><creatorcontrib>Wakamiya, Atsushi</creatorcontrib><creatorcontrib>Uemura, Daisuke</creatorcontrib><title>Relative stereochemistries of the ether rings and sugar moieties in durinskiol A</title><title>Tetrahedron letters</title><description>Durinskiol A ( 1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.</description><subject>Configuration determination</subject><subject>Durinskia</subject><subject>Glycosides</subject><subject>Molecular modeling</subject><subject>Natural products</subject><subject>Super-carbon-chain compounds</subject><issn>0040-4039</issn><issn>1873-3581</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNp9UE1LxDAQDaLguvoPPOTkreukTdv0IiyLX7CgiJ5Dm0x2s3YbTdIF_71Z6tlhmIGZ94Y3j5BrBgsGrLrdLSLGHuMiB6gXUKRsTsiMibrIilKwUzID4JDxND8nFyHsIEUlYEZe37Bvoz0gDRE9OrXFvQ3RWwzUGRq3SDEVT70dNoG2g6Zh3LSe7p3FeETZgeoxbcOndT1dXpIz0_YBr_76nHw83L-vnrL1y-PzarnOVFIRs7IWphRNks-RQacMV0JojlWFuRE6r0WjOy54xxpQpuA1iByqril1zbUxrJiTm-nul3ffI4Yok26Ffd8O6MYgc5bzMj2fgHwCKu9C8Gjkl7f71v9IBvJon9zJyT55tE9CkbJJtLuJhumJg0Uvg7I4KNTWo4pSO_v_gV_plHs4</recordid><startdate>20070501</startdate><enddate>20070501</enddate><creator>Kita, Masaki</creator><creator>Roy, Michael C.</creator><creator>Siwu, Eric R.O.</creator><creator>Noma, Isao</creator><creator>Takiguchi, Takahiro</creator><creator>Yamada, Kaoru</creator><creator>Koyama, Tomoyuki</creator><creator>Iwashita, Takeshi</creator><creator>Wakamiya, Atsushi</creator><creator>Uemura, Daisuke</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>M7N</scope></search><sort><creationdate>20070501</creationdate><title>Relative stereochemistries of the ether rings and sugar moieties in durinskiol A</title><author>Kita, Masaki ; Roy, Michael C. ; Siwu, Eric R.O. ; Noma, Isao ; Takiguchi, Takahiro ; Yamada, Kaoru ; Koyama, Tomoyuki ; Iwashita, Takeshi ; Wakamiya, Atsushi ; Uemura, Daisuke</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c403t-578f5891014e10bcf4c88d4e66e2f8d2789db484b190cf34708206b95d74dff13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Configuration determination</topic><topic>Durinskia</topic><topic>Glycosides</topic><topic>Molecular modeling</topic><topic>Natural products</topic><topic>Super-carbon-chain compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kita, Masaki</creatorcontrib><creatorcontrib>Roy, Michael C.</creatorcontrib><creatorcontrib>Siwu, Eric R.O.</creatorcontrib><creatorcontrib>Noma, Isao</creatorcontrib><creatorcontrib>Takiguchi, Takahiro</creatorcontrib><creatorcontrib>Yamada, Kaoru</creatorcontrib><creatorcontrib>Koyama, Tomoyuki</creatorcontrib><creatorcontrib>Iwashita, Takeshi</creatorcontrib><creatorcontrib>Wakamiya, Atsushi</creatorcontrib><creatorcontrib>Uemura, Daisuke</creatorcontrib><collection>CrossRef</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><jtitle>Tetrahedron letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kita, Masaki</au><au>Roy, Michael C.</au><au>Siwu, Eric R.O.</au><au>Noma, Isao</au><au>Takiguchi, Takahiro</au><au>Yamada, Kaoru</au><au>Koyama, Tomoyuki</au><au>Iwashita, Takeshi</au><au>Wakamiya, Atsushi</au><au>Uemura, Daisuke</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Relative stereochemistries of the ether rings and sugar moieties in durinskiol A</atitle><jtitle>Tetrahedron letters</jtitle><date>2007-05-01</date><risdate>2007</risdate><volume>48</volume><issue>19</issue><spage>3429</spage><epage>3432</epage><pages>3429-3432</pages><issn>0040-4039</issn><eissn>1873-3581</eissn><abstract>Durinskiol A ( 1) is a long carbon-chain polyol compound with a molecular weight of 2128 mu isolated from the symbiotic dinoflagellate Durinskia sp. The relative stereochemistries of ether rings and sugar moieties in 1 were established based on 2D-NMR analysis and molecular modeling studies. Conformational analysis of the 6,5,6-bis-spiroacetal ring in 1 was also examined by using ab initio methods.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.tetlet.2007.03.039</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0040-4039
ispartof Tetrahedron letters, 2007-05, Vol.48 (19), p.3429-3432
issn 0040-4039
1873-3581
language eng
recordid cdi_proquest_miscellaneous_21245358
source Elsevier ScienceDirect Journals Complete
subjects Configuration determination
Durinskia
Glycosides
Molecular modeling
Natural products
Super-carbon-chain compounds
title Relative stereochemistries of the ether rings and sugar moieties in durinskiol A
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T08%3A45%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Relative%20stereochemistries%20of%20the%20ether%20rings%20and%20sugar%20moieties%20in%20durinskiol%20A&rft.jtitle=Tetrahedron%20letters&rft.au=Kita,%20Masaki&rft.date=2007-05-01&rft.volume=48&rft.issue=19&rft.spage=3429&rft.epage=3432&rft.pages=3429-3432&rft.issn=0040-4039&rft.eissn=1873-3581&rft_id=info:doi/10.1016/j.tetlet.2007.03.039&rft_dat=%3Cproquest_cross%3E21245358%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=21245358&rft_id=info:pmid/&rft_els_id=S0040403907004820&rfr_iscdi=true