Model Complexes for the Nip Site of Acetyl Coenzyme A Synthase/Carbon Monoxide (CO) Dehydrogenase: Structure, Electrochemistry, and CO Reactivity

Aliphatic thiolato-S-bridged tri- and binuclear nickel­(II) complexes have been synthesized and characterized as models for the Nip site of the A cluster of acetyl coenzyme A synthase (ACS)/carbon monooxide (CO) dehydrogenase. Reaction of the in situ formed N2Sthiol donor ligands with [Ni­(H2O)6]­(C...

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Veröffentlicht in:	Inorganic chemistry 2018-11, Vol.57 (21), p.13713-13727
Hauptverfasser:	Bhandari, Anirban, Chandra Maji, Ram, Mishra, Saikat, Kumar, Akhilesh, Barman, Suman Kumar, Das, Partha Pratim, Ghiassi, Kamran B, Olmstead, Marilyn M, Patra, Apurba K
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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