Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing
Gate-opening gas sorption is known for metal-organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas uptake. Here, we show that gate-opening is also possible for metal-organic polyhedra (MOPs), and depends on the molecular organisation in the...
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| Veröffentlicht in: | Chemical science (Cambridge) 2018-08, Vol.9 (31), p.6463-6469 |
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| creator | Craig, Gavin A Larpent, Patrick Kusaka, Shinpei Matsuda, Ryotaro Kitagawa, Susumu Furukawa, Shuhei |
| description | Gate-opening gas sorption is known for metal-organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas uptake. Here, we show that gate-opening is also possible for metal-organic polyhedra (MOPs), and depends on the molecular organisation in the lattice. Thanks to the solubility of MOPs, several interchangeable solvatomorphs of a lantern-type MOP were synthesised
treatment with different solvents. One phase obtained through use of methanol induced a gate-opening effect in the lattice in response to carbon dioxide uptake. The sorption process was thoroughly investigated with
powder X-ray diffraction and simultaneous adsorption experiments. Meanwhile, solution processing of this flexible phase using THF led to a permanently porous phase without a gate-opening effect. Furthermore, we find that we can change the metallic composition of the MOP, and yet retain flexibility. By showing that gate-opening can be switched on and off depending on the solvent of crystallisation, these findings have implications for the solution-based processing of MOPs. |
| doi_str_mv | 10.1039/c8sc02263a |
| format | Article |
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treatment with different solvents. One phase obtained through use of methanol induced a gate-opening effect in the lattice in response to carbon dioxide uptake. The sorption process was thoroughly investigated with
powder X-ray diffraction and simultaneous adsorption experiments. Meanwhile, solution processing of this flexible phase using THF led to a permanently porous phase without a gate-opening effect. Furthermore, we find that we can change the metallic composition of the MOP, and yet retain flexibility. By showing that gate-opening can be switched on and off depending on the solvent of crystallisation, these findings have implications for the solution-based processing of MOPs.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c8sc02263a</identifier><identifier>PMID: 30310576</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbon dioxide ; Chemistry ; Crystallization ; Flexibility ; Metal-organic frameworks ; Mopping ; Polyhedra ; Sorption ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Chemical science (Cambridge), 2018-08, Vol.9 (31), p.6463-6469</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><rights>This journal is © The Royal Society of Chemistry 2018 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c516t-233d468ca702c113233a08ffa1178d1d4a556533a657111f5010815db69eeb2c3</citedby><cites>FETCH-LOGICAL-c516t-233d468ca702c113233a08ffa1178d1d4a556533a657111f5010815db69eeb2c3</cites><orcidid>0000-0002-7665-6212 ; 0000-0003-3849-8038 ; 0000-0001-7718-4387 ; 0000-0003-3542-4850</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115636/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC6115636/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27922,27923,53789,53791</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30310576$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Craig, Gavin A</creatorcontrib><creatorcontrib>Larpent, Patrick</creatorcontrib><creatorcontrib>Kusaka, Shinpei</creatorcontrib><creatorcontrib>Matsuda, Ryotaro</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Furukawa, Shuhei</creatorcontrib><title>Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing</title><title>Chemical science (Cambridge)</title><addtitle>Chem Sci</addtitle><description>Gate-opening gas sorption is known for metal-organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas uptake. Here, we show that gate-opening is also possible for metal-organic polyhedra (MOPs), and depends on the molecular organisation in the lattice. Thanks to the solubility of MOPs, several interchangeable solvatomorphs of a lantern-type MOP were synthesised
treatment with different solvents. One phase obtained through use of methanol induced a gate-opening effect in the lattice in response to carbon dioxide uptake. The sorption process was thoroughly investigated with
powder X-ray diffraction and simultaneous adsorption experiments. Meanwhile, solution processing of this flexible phase using THF led to a permanently porous phase without a gate-opening effect. Furthermore, we find that we can change the metallic composition of the MOP, and yet retain flexibility. By showing that gate-opening can be switched on and off depending on the solvent of crystallisation, these findings have implications for the solution-based processing of MOPs.</description><subject>Carbon dioxide</subject><subject>Chemistry</subject><subject>Crystallization</subject><subject>Flexibility</subject><subject>Metal-organic frameworks</subject><subject>Mopping</subject><subject>Polyhedra</subject><subject>Sorption</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkVFrFTEQhRdRbKl98QdIwBcRVjPJTTb7IpSLVqHQh9rnNJud3U3JbtYka-m_N9p6sc7LzDAfhzOcqnoN9ANQ3n60KlnKmOTmWXXM6A5qKXj7_DAzelSdpnRLS3EOgjUvqyNOOVDRyOPq5urOZTuZziMZTcY6rLi4ZSQ4DGgzcQuZMRtfhziaxVmyBn8_YR8NMSnh3HmHieQphm2cSAp-yy4sZI3BYkpF6FX1YjA-4eljP6muv3z-vv9aX1yef9ufXdRWgMw147zfSWVNQ5kF4GU3VA2DAWhUD_3OCFEe40aKBgAGQYEqEH0nW8SOWX5SfXrQXbduxt7ikqPxeo1uNvFeB-P008viJj2Gn1oCCMllEXj3KBDDjw1T1rNLFr03C4YtaQbQttA2ihf07X_obdjiUt7TjKqdaltG20K9f6BsDClFHA5mgOrf2em9utr_ye6swG_-tX9A_ybFfwFJPJUH</recordid><startdate>20180821</startdate><enddate>20180821</enddate><creator>Craig, Gavin A</creator><creator>Larpent, Patrick</creator><creator>Kusaka, Shinpei</creator><creator>Matsuda, Ryotaro</creator><creator>Kitagawa, Susumu</creator><creator>Furukawa, Shuhei</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-7665-6212</orcidid><orcidid>https://orcid.org/0000-0003-3849-8038</orcidid><orcidid>https://orcid.org/0000-0001-7718-4387</orcidid><orcidid>https://orcid.org/0000-0003-3542-4850</orcidid></search><sort><creationdate>20180821</creationdate><title>Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing</title><author>Craig, Gavin A ; Larpent, Patrick ; Kusaka, Shinpei ; Matsuda, Ryotaro ; Kitagawa, Susumu ; Furukawa, Shuhei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c516t-233d468ca702c113233a08ffa1178d1d4a556533a657111f5010815db69eeb2c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Carbon dioxide</topic><topic>Chemistry</topic><topic>Crystallization</topic><topic>Flexibility</topic><topic>Metal-organic frameworks</topic><topic>Mopping</topic><topic>Polyhedra</topic><topic>Sorption</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Craig, Gavin A</creatorcontrib><creatorcontrib>Larpent, Patrick</creatorcontrib><creatorcontrib>Kusaka, Shinpei</creatorcontrib><creatorcontrib>Matsuda, Ryotaro</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Furukawa, Shuhei</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Craig, Gavin A</au><au>Larpent, Patrick</au><au>Kusaka, Shinpei</au><au>Matsuda, Ryotaro</au><au>Kitagawa, Susumu</au><au>Furukawa, Shuhei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing</atitle><jtitle>Chemical science (Cambridge)</jtitle><addtitle>Chem Sci</addtitle><date>2018-08-21</date><risdate>2018</risdate><volume>9</volume><issue>31</issue><spage>6463</spage><epage>6469</epage><pages>6463-6469</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Gate-opening gas sorption is known for metal-organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas uptake. Here, we show that gate-opening is also possible for metal-organic polyhedra (MOPs), and depends on the molecular organisation in the lattice. Thanks to the solubility of MOPs, several interchangeable solvatomorphs of a lantern-type MOP were synthesised
treatment with different solvents. One phase obtained through use of methanol induced a gate-opening effect in the lattice in response to carbon dioxide uptake. The sorption process was thoroughly investigated with
powder X-ray diffraction and simultaneous adsorption experiments. Meanwhile, solution processing of this flexible phase using THF led to a permanently porous phase without a gate-opening effect. Furthermore, we find that we can change the metallic composition of the MOP, and yet retain flexibility. By showing that gate-opening can be switched on and off depending on the solvent of crystallisation, these findings have implications for the solution-based processing of MOPs.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30310576</pmid><doi>10.1039/c8sc02263a</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-7665-6212</orcidid><orcidid>https://orcid.org/0000-0003-3849-8038</orcidid><orcidid>https://orcid.org/0000-0001-7718-4387</orcidid><orcidid>https://orcid.org/0000-0003-3542-4850</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; EZB-FREE-00999 freely available EZB journals; PubMed Central |
| subjects | Carbon dioxide Chemistry Crystallization Flexibility Metal-organic frameworks Mopping Polyhedra Sorption X ray powder diffraction X-ray diffraction |
| title | Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing |
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