Rationally designing mixed Cu-(μ-O)-M (M = Cu, Ag, Zn, Au) centers over zeolite materials with high catalytic activity towards methane activation

The direct conversion of methane to methanol on [Cu(μ-O)M] (M = Cu, Ag, Zn, Au) bimetal centers in ZSM-5 zeolite is investigated using periodic density functional theory for the first time. Some conclusions are drawn: (1) methane activation on [Cu(μ-O)M] (M = Cu, Ag, Zn, Au) in the ZSM-5 zeolite pro...

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