Cobalt complexes with hemilabile o-iminobenzoquinonate ligands: a novel example of redox-induced electron transfer

The tetracoordinated square-planar CoIII complex (imSQC(O)Ph)CoIII(APC(O)Ph) (1) bearing a radical anion and the closed-shell o-amidophenolate forms of the functionalized o-aminophenol H2LC(O)Ph were synthesized. The intermediate spin state (SCo = 1) CoIII center was found for compound 1. The cyclic...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018-10, Vol.47 (42), p.15049-15060
Hauptverfasser:	Piskunov, Alexandr V, Pashanova, Kira I, Bogomyakov, Artem S, Smolyaninov, Ivan V, Starikov, Andrey G, Fukin, Georgy K
Format:	Artikel
Sprache:	eng
Schlagworte:	Aminophenol Antiferromagnetism Cobalt compounds Coordination compounds Crystallography Data acquisition Density functional theory Electron transfer Electrons Format Ligands Organic chemistry Oxidation Silver Valence
Online-Zugang:	Volltext
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