Molecular Bottlebrushes as Novel Materials

Molecular bottlebrushes are building blocks for the design of unique polymeric materials whose physical properties are fundamentally governed by their densely grafted structures. Recent developments in the area of reversible deactivation radical polymerization enabled facile and effective control ov...

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Veröffentlicht in:Biomacromolecules 2019-01, Vol.20 (1), p.27-54
Hauptverfasser: Xie, Guojun, Martinez, Michael R, Olszewski, Mateusz, Sheiko, Sergei S, Matyjaszewski, Krzysztof
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container_end_page 54
container_issue 1
container_start_page 27
container_title Biomacromolecules
container_volume 20
creator Xie, Guojun
Martinez, Michael R
Olszewski, Mateusz
Sheiko, Sergei S
Matyjaszewski, Krzysztof
description Molecular bottlebrushes are building blocks for the design of unique polymeric materials whose physical properties are fundamentally governed by their densely grafted structures. Recent developments in the area of reversible deactivation radical polymerization enabled facile and effective control over multiple molecular parameters. Owing to large molecular size, anisotropic conformation, and reduced chain entanglement, molecular bottlebrushes have empowered various applications that are challenging to achieve with linear polymers. In this Review, we focus on determining correlations between brushlike architectures and materials properties.
doi_str_mv 10.1021/acs.biomac.8b01171
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subjects Chemistry Techniques, Synthetic - methods
Elastomers - chemical synthesis
Nanostructures - chemistry
Nanostructures - ultrastructure
Polymerization
Surface-Active Agents - chemical synthesis
title Molecular Bottlebrushes as Novel Materials
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