Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts
Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall metal nanoparticles (MNPs) inside their void nanospaces to generate high‐efficiency nanocatalysts. The nanopore‐encaged me...
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| Veröffentlicht in: | Advanced materials (Weinheim) 2019-01, Vol.31 (1), p.e1803966-n/a |
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| creator | Wang, Ning Sun, Qiming Yu, Jihong |
| description | Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall metal nanoparticles (MNPs) inside their void nanospaces to generate high‐efficiency nanocatalysts. The nanopore‐encaged metal catalysts exhibit superior catalytic performance as well as high stability and catalytic shape selectivity endowed by the nanoporous matrix. In addition, the synergistic effect of confined MNPs and nanoporous frameworks with active sites can further promote the catalytic activities of the composite catalysts. Herein, recent progress in nanopore‐encaged metal nanocatalysts is reviewed, with a special focus on advances in synthetic strategies for ultrasmall MNPs ( |
| doi_str_mv | 10.1002/adma.201803966 |
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Recent advancements in nanopore‐encaged metal nanocatalysts are reviewed, mainly focusing on presenting the state‐of‐the‐art strategies for the fabrication of ultrasmall metal nanoparticles (<5 nm), clusters, and even single atoms confined within crystalline nanoporous materials including zeolites and metal–organic frameworks. Some related catalytic applications and advanced characterization methods are introduced, and the current limitations of and future opportunities for these fantastic nanocatalysts are also highlighted.</description><identifier>ISSN: 0935-9648</identifier><identifier>EISSN: 1521-4095</identifier><identifier>DOI: 10.1002/adma.201803966</identifier><identifier>PMID: 30276888</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Catalysis ; Catalysts ; Chemical synthesis ; confinement synthesis ; Crystal structure ; Crystallinity ; Metal-organic frameworks ; nanocatalysts ; Nanoparticles ; Porosity ; Porous materials ; Selectivity ; Synergistic effect ; ultrasmall metal nanoparticles ; Zeolites</subject><ispartof>Advanced materials (Weinheim), 2019-01, Vol.31 (1), p.e1803966-n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5166-12ff234ae3f94d013de7c1bd192bfe924658d2cfb30f5b19407019ac8e09d7b83</citedby><cites>FETCH-LOGICAL-c5166-12ff234ae3f94d013de7c1bd192bfe924658d2cfb30f5b19407019ac8e09d7b83</cites><orcidid>0000-0003-1615-5034</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadma.201803966$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadma.201803966$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27926,27927,45576,45577</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30276888$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Ning</creatorcontrib><creatorcontrib>Sun, Qiming</creatorcontrib><creatorcontrib>Yu, Jihong</creatorcontrib><title>Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts</title><title>Advanced materials (Weinheim)</title><addtitle>Adv Mater</addtitle><description>Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall metal nanoparticles (MNPs) inside their void nanospaces to generate high‐efficiency nanocatalysts. The nanopore‐encaged metal catalysts exhibit superior catalytic performance as well as high stability and catalytic shape selectivity endowed by the nanoporous matrix. In addition, the synergistic effect of confined MNPs and nanoporous frameworks with active sites can further promote the catalytic activities of the composite catalysts. Herein, recent progress in nanopore‐encaged metal nanocatalysts is reviewed, with a special focus on advances in synthetic strategies for ultrasmall MNPs (<5 nm), clusters, and even single atoms confined within zeolites and MOFs for various heterogeneous catalytic reactions. In addition, some advanced characterization methods to elucidate the atomic‐scale structures of the nanocatalysts are presented, and the current limitations of and future opportunities for these fantastic nanocatalysts are also highlighted and discussed. The aim is to provide some guidance for the rational synthesis of nanopore‐encaged metal catalysts and to inspire their further applications to meet the emerging demands in catalytic fields.
Recent advancements in nanopore‐encaged metal nanocatalysts are reviewed, mainly focusing on presenting the state‐of‐the‐art strategies for the fabrication of ultrasmall metal nanoparticles (<5 nm), clusters, and even single atoms confined within crystalline nanoporous materials including zeolites and metal–organic frameworks. Some related catalytic applications and advanced characterization methods are introduced, and the current limitations of and future opportunities for these fantastic nanocatalysts are also highlighted.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical synthesis</subject><subject>confinement synthesis</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Metal-organic frameworks</subject><subject>nanocatalysts</subject><subject>Nanoparticles</subject><subject>Porosity</subject><subject>Porous materials</subject><subject>Selectivity</subject><subject>Synergistic effect</subject><subject>ultrasmall metal nanoparticles</subject><subject>Zeolites</subject><issn>0935-9648</issn><issn>1521-4095</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqF0bFr3DAUBnBRWppL2jVjEXTp4uuTZMtStsNN0kCuXZrZPMtSqiDbV8km3H8fJZemkKWTQPy-jwcfIacM1gyAf8V-wDUHpkBoKd-QFas4K0rQ1VuyAi2qQstSHZHjlO4AQEuQ78mRAF5LpdSKLDdhjpgGDIFu7YyB_sBx2mGcvQk20WYanR9tT-_9_NuPtIn7lFXIfwc5xWlJdIuzjR5DOqMbeoHJ-BFnP97SJmBKdHJP2GCO5nz6QN65jO3H5_eE3Fyc_2q-F9c_L6-azXVhKiZlwbhzXJRohdNlD0z0tjas65nmnbOal7JSPTeuE-CqjukSamAajbKg-7pT4oR8OfTu4vRnsWluB5-MDQFHm89uOWNVXdVlKTL9_IreTUsc83VZSV5zAYpltT4oE6eUonXtLvoB475l0D4O0j4O0r4MkgOfnmuXbrD9C_-7QAb6AO59sPv_1LWbb9vNv_IHeXGYhg</recordid><startdate>201901</startdate><enddate>201901</enddate><creator>Wang, Ning</creator><creator>Sun, Qiming</creator><creator>Yu, Jihong</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1615-5034</orcidid></search><sort><creationdate>201901</creationdate><title>Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts</title><author>Wang, Ning ; Sun, Qiming ; Yu, Jihong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5166-12ff234ae3f94d013de7c1bd192bfe924658d2cfb30f5b19407019ac8e09d7b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical synthesis</topic><topic>confinement synthesis</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Metal-organic frameworks</topic><topic>nanocatalysts</topic><topic>Nanoparticles</topic><topic>Porosity</topic><topic>Porous materials</topic><topic>Selectivity</topic><topic>Synergistic effect</topic><topic>ultrasmall metal nanoparticles</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Ning</creatorcontrib><creatorcontrib>Sun, Qiming</creatorcontrib><creatorcontrib>Yu, Jihong</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Advanced materials (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Ning</au><au>Sun, Qiming</au><au>Yu, Jihong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts</atitle><jtitle>Advanced materials (Weinheim)</jtitle><addtitle>Adv Mater</addtitle><date>2019-01</date><risdate>2019</risdate><volume>31</volume><issue>1</issue><spage>e1803966</spage><epage>n/a</epage><pages>e1803966-n/a</pages><issn>0935-9648</issn><eissn>1521-4095</eissn><abstract>Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall metal nanoparticles (MNPs) inside their void nanospaces to generate high‐efficiency nanocatalysts. The nanopore‐encaged metal catalysts exhibit superior catalytic performance as well as high stability and catalytic shape selectivity endowed by the nanoporous matrix. In addition, the synergistic effect of confined MNPs and nanoporous frameworks with active sites can further promote the catalytic activities of the composite catalysts. Herein, recent progress in nanopore‐encaged metal nanocatalysts is reviewed, with a special focus on advances in synthetic strategies for ultrasmall MNPs (<5 nm), clusters, and even single atoms confined within zeolites and MOFs for various heterogeneous catalytic reactions. In addition, some advanced characterization methods to elucidate the atomic‐scale structures of the nanocatalysts are presented, and the current limitations of and future opportunities for these fantastic nanocatalysts are also highlighted and discussed. The aim is to provide some guidance for the rational synthesis of nanopore‐encaged metal catalysts and to inspire their further applications to meet the emerging demands in catalytic fields.
Recent advancements in nanopore‐encaged metal nanocatalysts are reviewed, mainly focusing on presenting the state‐of‐the‐art strategies for the fabrication of ultrasmall metal nanoparticles (<5 nm), clusters, and even single atoms confined within crystalline nanoporous materials including zeolites and metal–organic frameworks. Some related catalytic applications and advanced characterization methods are introduced, and the current limitations of and future opportunities for these fantastic nanocatalysts are also highlighted.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>30276888</pmid><doi>10.1002/adma.201803966</doi><tpages>23</tpages><orcidid>https://orcid.org/0000-0003-1615-5034</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Catalysis Catalysts Chemical synthesis confinement synthesis Crystal structure Crystallinity Metal-organic frameworks nanocatalysts Nanoparticles Porosity Porous materials Selectivity Synergistic effect ultrasmall metal nanoparticles Zeolites |
| title | Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts |
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