Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines

Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines

The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile hydrogenation. A variety of aromatic and aliphat...

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Veröffentlicht in:Organic letters 2018-10, Vol.20 (20), p.6430-6435
Hauptverfasser: Li, Huaifeng, Al-Dakhil, Abdullah, Lupp, Daniel, Gholap, Sandeep Suryabhan, Lai, Zhiping, Liang, Lan-Chang, Huang, Kuo-Wei
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container_end_page 6435
container_issue 20
container_start_page 6430
container_title Organic letters
container_volume 20
creator Li, Huaifeng
Al-Dakhil, Abdullah
Lupp, Daniel
Gholap, Sandeep Suryabhan
Lai, Zhiping
Liang, Lan-Chang
Huang, Kuo-Wei
description The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile hydrogenation. A variety of aromatic and aliphatic nitriles are hydrogenated to the corresponding secondary imines.
doi_str_mv 10.1021/acs.orglett.8b02744
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title Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines
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