Influence of Structural (Cation and Anion) Order in the Superconducting Properties of Ozone-Oxidized Mo0.3Cu0.7Sr2RECu2O y (RE = Yb, Tm, Gd, Nd, and Pr)

Influence of Structural (Cation and Anion) Order in the Superconducting Properties of Ozone-Oxidized Mo0.3Cu0.7Sr2RECu2O y (RE = Yb, Tm, Gd, Nd, and Pr)

The influence of rare earth (RE) elements on superconducting properties of the transition element (TE)-substituted TE x Cu1–x Sr2RECu2O y cuprates has not been sufficiently emphasized so far. In the case of molibdo-cuprates with the general formula Mo0.3Cu0.3Sr2RECu2O y , all the RE element containi...

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Veröffentlicht in:Inorganic chemistry 2018-10, Vol.57 (19), p.12038-12049
Hauptverfasser: Martínez de Irujo-Labalde, Xabier, Urones-Garrote, Esteban, García-Martín, Susana, Alario-Franco, Miguel Ángel
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container_end_page 12049
container_issue 19
container_start_page 12038
container_title Inorganic chemistry
container_volume 57
creator Martínez de Irujo-Labalde, Xabier
Urones-Garrote, Esteban
García-Martín, Susana
Alario-Franco, Miguel Ángel
description The influence of rare earth (RE) elements on superconducting properties of the transition element (TE)-substituted TE x Cu1–x Sr2RECu2O y cuprates has not been sufficiently emphasized so far. In the case of molibdo-cuprates with the general formula Mo0.3Cu0.3Sr2RECu2O y , all the RE element containing compounds except La, Ce, and Lu can be prepared at room pressure. The influence of the crystal structure on the superconducting properties after ozone oxidation of the present system is reported selecting three groups of RE elements attending to their different atom sizes: small (Yb and Tm), medium (Gd), and big (Nd and Pr). Advanced transmission electron microscopy, various diffraction techniques, and spectroscopic analysis have been used to demonstrate that the increase of structural disorder complemented with a decrease in the hole content play a major role in the vanishing of superconductivity within the present system.
doi_str_mv 10.1021/acs.inorgchem.8b01594
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title Influence of Structural (Cation and Anion) Order in the Superconducting Properties of Ozone-Oxidized Mo0.3Cu0.7Sr2RECu2O y (RE = Yb, Tm, Gd, Nd, and Pr)
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