Stimuli‐Responsive Properties of Aggregation‐Induced‐Emission Compounds Containing a 9,10‐Distyrylanthracene Moiety
Two 9,10‐distyrylanthracene‐based luminophores exhibiting aggregation‐induced emission and stimuli‐responsive properties were synthesized. Seven‐ or five‐color luminescence switching based on a single organic molecule was achieved for the first time. These phase transitions can be induced by physica...
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| Veröffentlicht in: | Chemistry : a European journal 2018-12, Vol.24 (71), p.19053-19059 |
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| container_issue | 71 |
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| container_title | Chemistry : a European journal |
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| creator | Jia, Xiang‐Rui Yu, Hui‐Juan Chen, Jian Gao, Wei‐Jie Fang, Jing‐Kun Qin, Yuan‐Shou Hu, Xiao‐Kai Shao, Guang |
| description | Two 9,10‐distyrylanthracene‐based luminophores exhibiting aggregation‐induced emission and stimuli‐responsive properties were synthesized. Seven‐ or five‐color luminescence switching based on a single organic molecule was achieved for the first time. These phase transitions can be induced by physical stimuli such as grinding by mortar and pestle, heating, and exposure to the vapors of organic solvents. Moreover, a strategy for the design of new mechanoresponsive materials with π‐conjugated luminophores is proposed.
Seven‐color luminophore: Piezochromism based on aggregation‐induced emission with distinct seven‐color luminescence switching built on a single organic molecule was achieved for the first time. The fluorescence switching process (see figure) can be smoothly triggered by disrupting the ordered molecular packing (mechanical grinding) and repacking (heating or solvent annealing). |
| doi_str_mv | 10.1002/chem.201804315 |
| format | Article |
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Seven‐color luminophore: Piezochromism based on aggregation‐induced emission with distinct seven‐color luminescence switching built on a single organic molecule was achieved for the first time. The fluorescence switching process (see figure) can be smoothly triggered by disrupting the ordered molecular packing (mechanical grinding) and repacking (heating or solvent annealing).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201804315</identifier><identifier>PMID: 30222213</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Agglomeration ; aggregation-induced emission ; Chemistry ; chromophores ; Emission ; fluorescence ; Mortars (comminutors) ; Organic solvents ; Phase transitions ; piezochromism ; Stimuli ; stimuli-responsive materials ; Vapors</subject><ispartof>Chemistry : a European journal, 2018-12, Vol.24 (71), p.19053-19059</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4105-3914e14f12b571d416f78e8ebe9d75a1c15b4dc3f0b919d2c1e244480d0c5a2e3</citedby><cites>FETCH-LOGICAL-c4105-3914e14f12b571d416f78e8ebe9d75a1c15b4dc3f0b919d2c1e244480d0c5a2e3</cites><orcidid>0000-0003-2606-2640 ; 0000-0002-0077-5629</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201804315$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201804315$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30222213$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Jia, Xiang‐Rui</creatorcontrib><creatorcontrib>Yu, Hui‐Juan</creatorcontrib><creatorcontrib>Chen, Jian</creatorcontrib><creatorcontrib>Gao, Wei‐Jie</creatorcontrib><creatorcontrib>Fang, Jing‐Kun</creatorcontrib><creatorcontrib>Qin, Yuan‐Shou</creatorcontrib><creatorcontrib>Hu, Xiao‐Kai</creatorcontrib><creatorcontrib>Shao, Guang</creatorcontrib><title>Stimuli‐Responsive Properties of Aggregation‐Induced‐Emission Compounds Containing a 9,10‐Distyrylanthracene Moiety</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Two 9,10‐distyrylanthracene‐based luminophores exhibiting aggregation‐induced emission and stimuli‐responsive properties were synthesized. Seven‐ or five‐color luminescence switching based on a single organic molecule was achieved for the first time. These phase transitions can be induced by physical stimuli such as grinding by mortar and pestle, heating, and exposure to the vapors of organic solvents. Moreover, a strategy for the design of new mechanoresponsive materials with π‐conjugated luminophores is proposed.
Seven‐color luminophore: Piezochromism based on aggregation‐induced emission with distinct seven‐color luminescence switching built on a single organic molecule was achieved for the first time. The fluorescence switching process (see figure) can be smoothly triggered by disrupting the ordered molecular packing (mechanical grinding) and repacking (heating or solvent annealing).</description><subject>Agglomeration</subject><subject>aggregation-induced emission</subject><subject>Chemistry</subject><subject>chromophores</subject><subject>Emission</subject><subject>fluorescence</subject><subject>Mortars (comminutors)</subject><subject>Organic solvents</subject><subject>Phase transitions</subject><subject>piezochromism</subject><subject>Stimuli</subject><subject>stimuli-responsive materials</subject><subject>Vapors</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkU1v1DAQhi1ERZeFK0cUiQsHsnj8kcTHallopVZFfJyjxJ5sXSV2sBNQxIWfwG_kl9TVtkXiwlxmNHrm1at5CXkBdAOUsrf6CocNo1BRwUE-IiuQDHJeFvIxWVElyryQXB2TpzFeU0pVwfkTcswpSwV8RX5-nuww9_bPr9-fMI7eRfsds4_BjxgmizHzXXay3wfcN5P1LmFnzswaTZp2g40xLbOtH0Y_OxPT5KbGOuv2WZOpN0AT9s7GaQlL37jpKjQaHWYX3uK0PCNHXdNHfH7X1-Tr-92X7Wl-fvnhbHtynmsBVOZcgUAQHbBWlmAEFF1ZYYUtKlPKBjTIVhjNO9oqUIZpQCaEqKihWjYM-Zq8PuiOwX-bMU51Mq6xT47Qz7FmQCtWMJ6esyav_kGv_RxccpcoWSpRiEomanOgdPAxBuzqMdihCUsNtL6Npb6NpX6IJR28vJOd2wHNA36fQwLUAfhhe1z-I1dvT3cXf8VvAFhRnj0</recordid><startdate>20181217</startdate><enddate>20181217</enddate><creator>Jia, Xiang‐Rui</creator><creator>Yu, Hui‐Juan</creator><creator>Chen, Jian</creator><creator>Gao, Wei‐Jie</creator><creator>Fang, Jing‐Kun</creator><creator>Qin, Yuan‐Shou</creator><creator>Hu, Xiao‐Kai</creator><creator>Shao, Guang</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2606-2640</orcidid><orcidid>https://orcid.org/0000-0002-0077-5629</orcidid></search><sort><creationdate>20181217</creationdate><title>Stimuli‐Responsive Properties of Aggregation‐Induced‐Emission Compounds Containing a 9,10‐Distyrylanthracene Moiety</title><author>Jia, Xiang‐Rui ; Yu, Hui‐Juan ; Chen, Jian ; Gao, Wei‐Jie ; Fang, Jing‐Kun ; Qin, Yuan‐Shou ; Hu, Xiao‐Kai ; Shao, Guang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4105-3914e14f12b571d416f78e8ebe9d75a1c15b4dc3f0b919d2c1e244480d0c5a2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Agglomeration</topic><topic>aggregation-induced emission</topic><topic>Chemistry</topic><topic>chromophores</topic><topic>Emission</topic><topic>fluorescence</topic><topic>Mortars (comminutors)</topic><topic>Organic solvents</topic><topic>Phase transitions</topic><topic>piezochromism</topic><topic>Stimuli</topic><topic>stimuli-responsive materials</topic><topic>Vapors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jia, Xiang‐Rui</creatorcontrib><creatorcontrib>Yu, Hui‐Juan</creatorcontrib><creatorcontrib>Chen, Jian</creatorcontrib><creatorcontrib>Gao, Wei‐Jie</creatorcontrib><creatorcontrib>Fang, Jing‐Kun</creatorcontrib><creatorcontrib>Qin, Yuan‐Shou</creatorcontrib><creatorcontrib>Hu, Xiao‐Kai</creatorcontrib><creatorcontrib>Shao, Guang</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Xiang‐Rui</au><au>Yu, Hui‐Juan</au><au>Chen, Jian</au><au>Gao, Wei‐Jie</au><au>Fang, Jing‐Kun</au><au>Qin, Yuan‐Shou</au><au>Hu, Xiao‐Kai</au><au>Shao, Guang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Stimuli‐Responsive Properties of Aggregation‐Induced‐Emission Compounds Containing a 9,10‐Distyrylanthracene Moiety</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2018-12-17</date><risdate>2018</risdate><volume>24</volume><issue>71</issue><spage>19053</spage><epage>19059</epage><pages>19053-19059</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Two 9,10‐distyrylanthracene‐based luminophores exhibiting aggregation‐induced emission and stimuli‐responsive properties were synthesized. Seven‐ or five‐color luminescence switching based on a single organic molecule was achieved for the first time. These phase transitions can be induced by physical stimuli such as grinding by mortar and pestle, heating, and exposure to the vapors of organic solvents. Moreover, a strategy for the design of new mechanoresponsive materials with π‐conjugated luminophores is proposed.
Seven‐color luminophore: Piezochromism based on aggregation‐induced emission with distinct seven‐color luminescence switching built on a single organic molecule was achieved for the first time. The fluorescence switching process (see figure) can be smoothly triggered by disrupting the ordered molecular packing (mechanical grinding) and repacking (heating or solvent annealing).</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>30222213</pmid><doi>10.1002/chem.201804315</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-2606-2640</orcidid><orcidid>https://orcid.org/0000-0002-0077-5629</orcidid></addata></record> |
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| subjects | Agglomeration aggregation-induced emission Chemistry chromophores Emission fluorescence Mortars (comminutors) Organic solvents Phase transitions piezochromism Stimuli stimuli-responsive materials Vapors |
| title | Stimuli‐Responsive Properties of Aggregation‐Induced‐Emission Compounds Containing a 9,10‐Distyrylanthracene Moiety |
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