Construction of a diverse set of terpenoid decalin subunits from a common enantiomerically pure scaffold obtained by a biomimetic cationic cyclization
An unprecedented biomimetic cationic cyclization reaction of an alkyne-containing geraniol-derived epoxide is used for the stereoselective synthesis of a novel enantiomerically pure scaffold that is easily transformed into a set of structurally diverse decalin derivatives with potential application...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2018-09, Vol.54 (78), p.1125-1128 |
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| container_issue | 78 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Fontaneda, Raquel Fañanás, Francisco J Rodríguez, Félix |
| description | An unprecedented biomimetic cationic cyclization reaction of an alkyne-containing geraniol-derived epoxide is used for the stereoselective synthesis of a novel enantiomerically pure scaffold that is easily transformed into a set of structurally diverse decalin derivatives with potential application in the synthesis of targeted natural products and/or natural-product-inspired new molecules.
An unprecedented biomimetic cationic cyclization reaction is used for the synthesis of an enantiomerically pure scaffold that is easily transformed into a set of structurally diverse decalin derivatives with potential application in the synthesis of targeted natural products and/or natural-product-inspired new molecules. |
| doi_str_mv | 10.1039/c8cc07281g |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2018-09, Vol.54 (78), p.1125-1128 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alkynes Biomimetics Cations Chemical synthesis Decalin Natural products Scaffolds Stereoselectivity |
| title | Construction of a diverse set of terpenoid decalin subunits from a common enantiomerically pure scaffold obtained by a biomimetic cationic cyclization |
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