Trimethylsilyl-Induced N–O Bond Cleavage in Nitrous Oxide-Derived Aminodiazotates

The chemical activation of nitrous oxide (N2O) typically results in O-atom transfer and the extrusion of N2 gas. In contrast, reactions of N-trimethylsilyl (TMS)-substituted amides with N2O give inorganic or organic azides, with concomitant formation of silanols or siloxanes. N-TMS-substituted amide...

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Veröffentlicht in:	Inorganic chemistry 2018-10, Vol.57 (19), p.11859-11863
Hauptverfasser:	Liu, Yizhu, Eymann, Léonard Y. M, Solari, Euro, Fadaei Tirani, Farzaneh, Scopelliti, Rosario, Severin, Kay
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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