Steric effects determine the mechanisms of reactions between bis(N-heterocyclic carbene)-nickel(0) complexes and aryl halides

Computational investigations of the reactions of [Ni(NHC) 2 ] complexes with aryl halides show that the outcomes are governed by the steric impact of the ligand (NHC = N-heterocyclic carbene). Small ligands permit facile oxidative addition, leading to Ni II complexes, while larger NHC ligands preven...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018, Vol.54 (75), p.1646-1649
Hauptverfasser:	Nelson, David J, Maseras, Feliu
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Computation Coordination compounds Halides Ligands Nickel Steric effects
Online-Zugang:	Volltext
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