Oxidative Coupling with Zr(IV) Supported by a Noninnocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines

We report the synthesis and reactivity of Zr complexes supported by a 9,10-anthracenediyl-linked bisphenoxide ligand, L. ZrIVLBn2 (1) undergoes facile photolytic reduction with concomitant formation of bibenzyl and ZrIVL­(THF)3 (2), which displays a two-electron reduced anthracene moiety. Leveraging...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-09, Vol.140 (38), p.11906-11910
Hauptverfasser:	Low, Choon Heng, Rosenberg, Jeffrey N, Lopez, Marco A, Agapie, Theodor
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes - chemistry Anthracenes - chemistry Catalysis Coordination Complexes - chemistry Cyclization Ligands Nitriles - chemistry Oxidative Coupling Pyrimidines - chemical synthesis Zirconium - chemistry
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