Modulating the cobalt redox potential through imidazole hydrogen bonding interactions in a supramolecular biomimetic protein-cofactor model

A realistic model for the active site of histidine-on cobalamin@protein complexes is reported and studied under homogeneous and immobilized conditions. Analysis of lower ligand modulation and its influence on the properties of the biomimetic compound are presented. The cofactor attachment by a prote...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (6), p.3836-3842
Hauptverfasser:	Sonnay, Marjorie, Fox, Thomas, Blacque, Olivier, Zelder, Felix
Format:	Artikel
Sprache:	eng
Schlagworte:	Biomimetics Coordination compounds Electrode potentials Hydrogen bonding Imidazole Ligands Modelling Modulation
Online-Zugang:	Volltext
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