Rhodium-Catalyzed B–H Bond Insertion Reactions of Unstabilized Diazo Compounds Generated in Situ from Tosylhydrazones

Although transition-metal-catalyzed B–H bond insertion of carbenes into stable borane adducts has emerged as a promising method for organoborane synthesis, all the diazo compounds used to date as carbene precursors have had an electron-withdrawing group to stabilize them. Herein, we report a protoco...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-08, Vol.140 (34), p.10663-10668
Hauptverfasser:	Pang, Yue, He, Qiao, Li, Zi-Qi, Yang, Ji-Min, Yu, Jin-Han, Zhu, Shou-Fei, Zhou, Qi-Lin
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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