Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor
Wastewater streams containing hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative....
Gespeichert in:
| Veröffentlicht in: | Environmental science and pollution research international 2018-10, Vol.25 (28), p.28489-28499 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 28499 |
|---|---|
| container_issue | 28 |
| container_start_page | 28489 |
| container_title | Environmental science and pollution research international |
| container_volume | 25 |
| creator | Terracciano, Amalia Ge, Jie Koutsospyros, Agamemnon Meng, Xiaoguang Smolinski, Benjamin Arienti, Per |
| description | Wastewater streams containing hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 h of reaction with GZVI, RDX was mainly converted to formaldehyde (CH
2
O), nitrate (NO
3
−
), and ammonium (NH
4
+
). Column filtration tests showed that pretreatment of the GZVI media with acid wash and low influent pH (4.0 ± 0.1) achieved 99% removal of RDX up to 5000 bed volume. BOD tests carried out on the post-treatment streams showed increased biodegradability of the treated wastewater, leading to a lower environmental impact for the final waste. |
| doi_str_mv | 10.1007/s11356-018-2871-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_2085658867</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2084666286</sourcerecordid><originalsourceid>FETCH-LOGICAL-c409t-3ed948fc6905575c16dbc3fd2abf88d7edd9f5d95759a742551a2fcbfdbec8473</originalsourceid><addsrcrecordid>eNp1kV9LHDEUxYNUdGv9AL6Ugb4oGJtkkkzyWNS6giBIC76FTP5oZDaxyUx1_fRm2W0tQp8u4fzOuZccAA4wOsEIdV8Lxi3jEGEBiegwFFtghjmmsKNSfgAzJCmFuKV0F3ws5QEhgiTpdsBui5AQhIoZSHP3rO-XNieIj9tjBsccYhj_feqXEF1zeHN2e9RkZyczhhSbftncZR2nQefmxVX-tx5cHJuQqxhiY1IcQ5zSVBo_pKfq1GZM-RPY9noobn8z98DP7-c_Tufw6vri8vTbFTQUyRG2zkoqvOESMdYxg7ntTest0b0XwnbOWumZlVWTuqOEMayJN723vTOCdu0eOFznPub0a3JlVItQjBsGHV29SREkGGdC8BX65R36kKYc63UrinLOieCVwmvK5FRKdl495rDQeakwUqs21LoNVdtQqzaUqJ7Pm-SpXzj71_Hn-ytA1kCpUrxz-W31_1NfAX3GlKg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2084666286</pqid></control><display><type>article</type><title>Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor</title><source>MEDLINE</source><source>SpringerLink Journals</source><creator>Terracciano, Amalia ; Ge, Jie ; Koutsospyros, Agamemnon ; Meng, Xiaoguang ; Smolinski, Benjamin ; Arienti, Per</creator><creatorcontrib>Terracciano, Amalia ; Ge, Jie ; Koutsospyros, Agamemnon ; Meng, Xiaoguang ; Smolinski, Benjamin ; Arienti, Per</creatorcontrib><description>Wastewater streams containing hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 h of reaction with GZVI, RDX was mainly converted to formaldehyde (CH
2
O), nitrate (NO
3
−
), and ammonium (NH
4
+
). Column filtration tests showed that pretreatment of the GZVI media with acid wash and low influent pH (4.0 ± 0.1) achieved 99% removal of RDX up to 5000 bed volume. BOD tests carried out on the post-treatment streams showed increased biodegradability of the treated wastewater, leading to a lower environmental impact for the final waste.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-018-2871-8</identifier><identifier>PMID: 30088248</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Ammonium ; Anoxic conditions ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biodegradability ; Biodegradation ; Continuous flow ; Digital media ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental impact ; Environmental science ; Filtration ; Hexahydro-1,3,5-trinitro-1,3,5-triazine ; Industrial Waste - analysis ; Industrial wastes ; Iron ; Iron - chemistry ; Models, Theoretical ; Nitrates ; Pretreatment ; RDX ; Reduction ; Research Article ; Streams ; Triazine ; Triazines - analysis ; Waste treatment ; Waste Water - chemistry ; Waste Water Technology ; Wastewater treatment ; Water Management ; Water Pollutants, Chemical - analysis ; Water Pollution Control ; Water Purification - methods</subject><ispartof>Environmental science and pollution research international, 2018-10, Vol.25 (28), p.28489-28499</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-3ed948fc6905575c16dbc3fd2abf88d7edd9f5d95759a742551a2fcbfdbec8473</citedby><cites>FETCH-LOGICAL-c409t-3ed948fc6905575c16dbc3fd2abf88d7edd9f5d95759a742551a2fcbfdbec8473</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-018-2871-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-018-2871-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30088248$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Terracciano, Amalia</creatorcontrib><creatorcontrib>Ge, Jie</creatorcontrib><creatorcontrib>Koutsospyros, Agamemnon</creatorcontrib><creatorcontrib>Meng, Xiaoguang</creatorcontrib><creatorcontrib>Smolinski, Benjamin</creatorcontrib><creatorcontrib>Arienti, Per</creatorcontrib><title>Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>Wastewater streams containing hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 h of reaction with GZVI, RDX was mainly converted to formaldehyde (CH
2
O), nitrate (NO
3
−
), and ammonium (NH
4
+
). Column filtration tests showed that pretreatment of the GZVI media with acid wash and low influent pH (4.0 ± 0.1) achieved 99% removal of RDX up to 5000 bed volume. BOD tests carried out on the post-treatment streams showed increased biodegradability of the treated wastewater, leading to a lower environmental impact for the final waste.</description><subject>Ammonium</subject><subject>Anoxic conditions</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biodegradability</subject><subject>Biodegradation</subject><subject>Continuous flow</subject><subject>Digital media</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental impact</subject><subject>Environmental science</subject><subject>Filtration</subject><subject>Hexahydro-1,3,5-trinitro-1,3,5-triazine</subject><subject>Industrial Waste - analysis</subject><subject>Industrial wastes</subject><subject>Iron</subject><subject>Iron - chemistry</subject><subject>Models, Theoretical</subject><subject>Nitrates</subject><subject>Pretreatment</subject><subject>RDX</subject><subject>Reduction</subject><subject>Research Article</subject><subject>Streams</subject><subject>Triazine</subject><subject>Triazines - analysis</subject><subject>Waste treatment</subject><subject>Waste Water - chemistry</subject><subject>Waste Water Technology</subject><subject>Wastewater treatment</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollution Control</subject><subject>Water Purification - methods</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>BENPR</sourceid><recordid>eNp1kV9LHDEUxYNUdGv9AL6Ugb4oGJtkkkzyWNS6giBIC76FTP5oZDaxyUx1_fRm2W0tQp8u4fzOuZccAA4wOsEIdV8Lxi3jEGEBiegwFFtghjmmsKNSfgAzJCmFuKV0F3ws5QEhgiTpdsBui5AQhIoZSHP3rO-XNieIj9tjBsccYhj_feqXEF1zeHN2e9RkZyczhhSbftncZR2nQefmxVX-tx5cHJuQqxhiY1IcQ5zSVBo_pKfq1GZM-RPY9noobn8z98DP7-c_Tufw6vri8vTbFTQUyRG2zkoqvOESMdYxg7ntTest0b0XwnbOWumZlVWTuqOEMayJN723vTOCdu0eOFznPub0a3JlVItQjBsGHV29SREkGGdC8BX65R36kKYc63UrinLOieCVwmvK5FRKdl495rDQeakwUqs21LoNVdtQqzaUqJ7Pm-SpXzj71_Hn-ytA1kCpUrxz-W31_1NfAX3GlKg</recordid><startdate>20181001</startdate><enddate>20181001</enddate><creator>Terracciano, Amalia</creator><creator>Ge, Jie</creator><creator>Koutsospyros, Agamemnon</creator><creator>Meng, Xiaoguang</creator><creator>Smolinski, Benjamin</creator><creator>Arienti, Per</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope></search><sort><creationdate>20181001</creationdate><title>Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor</title><author>Terracciano, Amalia ; Ge, Jie ; Koutsospyros, Agamemnon ; Meng, Xiaoguang ; Smolinski, Benjamin ; Arienti, Per</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-3ed948fc6905575c16dbc3fd2abf88d7edd9f5d95759a742551a2fcbfdbec8473</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Ammonium</topic><topic>Anoxic conditions</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biodegradability</topic><topic>Biodegradation</topic><topic>Continuous flow</topic><topic>Digital media</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental impact</topic><topic>Environmental science</topic><topic>Filtration</topic><topic>Hexahydro-1,3,5-trinitro-1,3,5-triazine</topic><topic>Industrial Waste - analysis</topic><topic>Industrial wastes</topic><topic>Iron</topic><topic>Iron - chemistry</topic><topic>Models, Theoretical</topic><topic>Nitrates</topic><topic>Pretreatment</topic><topic>RDX</topic><topic>Reduction</topic><topic>Research Article</topic><topic>Streams</topic><topic>Triazine</topic><topic>Triazines - analysis</topic><topic>Waste treatment</topic><topic>Waste Water - chemistry</topic><topic>Waste Water Technology</topic><topic>Wastewater treatment</topic><topic>Water Management</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollution Control</topic><topic>Water Purification - methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Terracciano, Amalia</creatorcontrib><creatorcontrib>Ge, Jie</creatorcontrib><creatorcontrib>Koutsospyros, Agamemnon</creatorcontrib><creatorcontrib>Meng, Xiaoguang</creatorcontrib><creatorcontrib>Smolinski, Benjamin</creatorcontrib><creatorcontrib>Arienti, Per</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>ABI/INFORM Complete</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Health and Medical</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>ProQuest Science Journals</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Terracciano, Amalia</au><au>Ge, Jie</au><au>Koutsospyros, Agamemnon</au><au>Meng, Xiaoguang</au><au>Smolinski, Benjamin</au><au>Arienti, Per</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2018-10-01</date><risdate>2018</risdate><volume>25</volume><issue>28</issue><spage>28489</spage><epage>28499</epage><pages>28489-28499</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>Wastewater streams containing hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) are subject to regulatory discharge regulations that require processing through industrial waste treatment. Thus, the development of easy-to-apply technologies for the treatment of RDX-laden wastewater streams is imperative. In the present study, the reduction of RDX by granular zero valent iron (GZVI) in batch and column experiments was investigated. Preliminary batch tests conducted under both oxic and anoxic conditions showed that after 3.0 h of reaction with GZVI, RDX was mainly converted to formaldehyde (CH
2
O), nitrate (NO
3
−
), and ammonium (NH
4
+
). Column filtration tests showed that pretreatment of the GZVI media with acid wash and low influent pH (4.0 ± 0.1) achieved 99% removal of RDX up to 5000 bed volume. BOD tests carried out on the post-treatment streams showed increased biodegradability of the treated wastewater, leading to a lower environmental impact for the final waste.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>30088248</pmid><doi>10.1007/s11356-018-2871-8</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0944-1344 |
| ispartof | Environmental science and pollution research international, 2018-10, Vol.25 (28), p.28489-28499 |
| issn | 0944-1344 1614-7499 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2085658867 |
| source | MEDLINE; SpringerLink Journals |
| subjects | Ammonium Anoxic conditions Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Biodegradability Biodegradation Continuous flow Digital media Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental impact Environmental science Filtration Hexahydro-1,3,5-trinitro-1,3,5-triazine Industrial Waste - analysis Industrial wastes Iron Iron - chemistry Models, Theoretical Nitrates Pretreatment RDX Reduction Research Article Streams Triazine Triazines - analysis Waste treatment Waste Water - chemistry Waste Water Technology Wastewater treatment Water Management Water Pollutants, Chemical - analysis Water Pollution Control Water Purification - methods |
| title | Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) reduction by granular zero-valent iron in continuous flow reactor |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-08T01%3A34%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Hexahydro-1,3,5-trinitro-1,3,5-triazine%20(RDX)%20reduction%20by%20granular%20zero-valent%20iron%20in%20continuous%20flow%20reactor&rft.jtitle=Environmental%20science%20and%20pollution%20research%20international&rft.au=Terracciano,%20Amalia&rft.date=2018-10-01&rft.volume=25&rft.issue=28&rft.spage=28489&rft.epage=28499&rft.pages=28489-28499&rft.issn=0944-1344&rft.eissn=1614-7499&rft_id=info:doi/10.1007/s11356-018-2871-8&rft_dat=%3Cproquest_cross%3E2084666286%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2084666286&rft_id=info:pmid/30088248&rfr_iscdi=true |