Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix
A dual-responsive supramolecular network based on pillar[6]arene–ferrocenium redox-controllable recognition motifs in polymeric backbones is constructed with a ferrocenium-functionalized copolymer and a pillar[6]arene copolymer, in which the first example of pillar[6]arene-functionalized copolyme...
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| Veröffentlicht in: | Macromolecules 2015-07, Vol.48 (13), p.4403-4409 |
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| container_end_page | 4409 |
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| container_issue | 13 |
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| container_title | Macromolecules |
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| creator | Xia, Wei Ni, Mengfei Yao, Chenhao Wang, Xiaoliang Chen, Dongzhong Lin, Chen Hu, Xiao-Yu Wang, Leyong |
| description | A dual-responsive supramolecular network based on pillar[6]arene–ferrocenium redox-controllable recognition motifs in polymeric backbones is constructed with a ferrocenium-functionalized copolymer and a pillar[6]arene copolymer, in which the first example of pillar[6]arene-functionalized copolymer was synthesized through the reversible addition/fragmentation chain-transfer copolymerization of an acrylate-functionalized pillar[6]arene and methyl acrylate. The resulting supramolecular network exhibits dramatically increased viscosity than the non-cross-linked mixtures and demonstrates a gel-like behavior on macroscale with a transient-network behavior revealed by rheology study. Furthermore, the viscoelastic properties of such supramolecular network can be easily controlled by different external stimuli including redox stimulus and competing host/guest reagents. |
| doi_str_mv | 10.1021/acs.macromol.5b00889 |
| format | Article |
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The resulting supramolecular network exhibits dramatically increased viscosity than the non-cross-linked mixtures and demonstrates a gel-like behavior on macroscale with a transient-network behavior revealed by rheology study. Furthermore, the viscoelastic properties of such supramolecular network can be easily controlled by different external stimuli including redox stimulus and competing host/guest reagents.</description><identifier>ISSN: 0024-9297</identifier><identifier>ISSN: 1520-5835</identifier><identifier>EISSN: 1520-5835</identifier><identifier>DOI: 10.1021/acs.macromol.5b00889</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>aromatic hydrocarbons ; composite polymers ; copolymerization ; rheology ; viscoelasticity ; viscosity</subject><ispartof>Macromolecules, 2015-07, Vol.48 (13), p.4403-4409</ispartof><rights>Copyright © American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a391t-902273ec16178d7d7276d6ddc421c3aa480ecffd6e72585e68008ad427691dcc3</citedby><cites>FETCH-LOGICAL-a391t-902273ec16178d7d7276d6ddc421c3aa480ecffd6e72585e68008ad427691dcc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acs.macromol.5b00889$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acs.macromol.5b00889$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,776,780,2752,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Xia, Wei</creatorcontrib><creatorcontrib>Ni, Mengfei</creatorcontrib><creatorcontrib>Yao, Chenhao</creatorcontrib><creatorcontrib>Wang, Xiaoliang</creatorcontrib><creatorcontrib>Chen, Dongzhong</creatorcontrib><creatorcontrib>Lin, Chen</creatorcontrib><creatorcontrib>Hu, Xiao-Yu</creatorcontrib><creatorcontrib>Wang, Leyong</creatorcontrib><title>Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix</title><title>Macromolecules</title><addtitle>Macromolecules</addtitle><description>A dual-responsive supramolecular network based on pillar[6]arene–ferrocenium redox-controllable recognition motifs in polymeric backbones is constructed with a ferrocenium-functionalized copolymer and a pillar[6]arene copolymer, in which the first example of pillar[6]arene-functionalized copolymer was synthesized through the reversible addition/fragmentation chain-transfer copolymerization of an acrylate-functionalized pillar[6]arene and methyl acrylate. The resulting supramolecular network exhibits dramatically increased viscosity than the non-cross-linked mixtures and demonstrates a gel-like behavior on macroscale with a transient-network behavior revealed by rheology study. Furthermore, the viscoelastic properties of such supramolecular network can be easily controlled by different external stimuli including redox stimulus and competing host/guest reagents.</description><subject>aromatic hydrocarbons</subject><subject>composite polymers</subject><subject>copolymerization</subject><subject>rheology</subject><subject>viscoelasticity</subject><subject>viscosity</subject><issn>0024-9297</issn><issn>1520-5835</issn><issn>1520-5835</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kE1OwzAQhS0EEqVwAxZeskmxnR8nS6hoQWoBFVghZBl7gtwmcbETSnfcgRtyEly1bFmNNPPe07wPoVNKBpQwei6VH9RSOVvbapC-EpLnxR7q0ZSRKM3jdB_1CGFJVLCCH6Ij7-eEUJomcQ-tZuCXtvHmA_AYqqgyC8AP3dLJkAWqq6TDt9CurFvgS-lBY9vge1OF_XP2Ih008PP1PQLnrILGdDWegbJvjWlNEE5ta0qPTbDYal2DMwpPZevM5zE6KGXl4WQ3--hpdPU4vI4md-Ob4cUkknFB26ggjPEYFM0ozzXXnPFMZ1qrhFEVS5nkBFRZ6gw4S_MUsjyUlzoJsoJqpeI-OtvmLp1978C3ojZeQfi_Adt5wUieEF4EVEGabKUBpPcOSrF0ppZuLSgRG84icBZ_nMWOc7CRrW1zndvONaHP_5ZfmeqITQ</recordid><startdate>20150714</startdate><enddate>20150714</enddate><creator>Xia, Wei</creator><creator>Ni, Mengfei</creator><creator>Yao, Chenhao</creator><creator>Wang, Xiaoliang</creator><creator>Chen, Dongzhong</creator><creator>Lin, Chen</creator><creator>Hu, Xiao-Yu</creator><creator>Wang, Leyong</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7S9</scope><scope>L.6</scope></search><sort><creationdate>20150714</creationdate><title>Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix</title><author>Xia, Wei ; Ni, Mengfei ; Yao, Chenhao ; Wang, Xiaoliang ; Chen, Dongzhong ; Lin, Chen ; Hu, Xiao-Yu ; Wang, Leyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a391t-902273ec16178d7d7276d6ddc421c3aa480ecffd6e72585e68008ad427691dcc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>aromatic hydrocarbons</topic><topic>composite polymers</topic><topic>copolymerization</topic><topic>rheology</topic><topic>viscoelasticity</topic><topic>viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xia, Wei</creatorcontrib><creatorcontrib>Ni, Mengfei</creatorcontrib><creatorcontrib>Yao, Chenhao</creatorcontrib><creatorcontrib>Wang, Xiaoliang</creatorcontrib><creatorcontrib>Chen, Dongzhong</creatorcontrib><creatorcontrib>Lin, Chen</creatorcontrib><creatorcontrib>Hu, Xiao-Yu</creatorcontrib><creatorcontrib>Wang, Leyong</creatorcontrib><collection>CrossRef</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><jtitle>Macromolecules</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xia, Wei</au><au>Ni, Mengfei</au><au>Yao, Chenhao</au><au>Wang, Xiaoliang</au><au>Chen, Dongzhong</au><au>Lin, Chen</au><au>Hu, Xiao-Yu</au><au>Wang, Leyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix</atitle><jtitle>Macromolecules</jtitle><addtitle>Macromolecules</addtitle><date>2015-07-14</date><risdate>2015</risdate><volume>48</volume><issue>13</issue><spage>4403</spage><epage>4409</epage><pages>4403-4409</pages><issn>0024-9297</issn><issn>1520-5835</issn><eissn>1520-5835</eissn><abstract>A dual-responsive supramolecular network based on pillar[6]arene–ferrocenium redox-controllable recognition motifs in polymeric backbones is constructed with a ferrocenium-functionalized copolymer and a pillar[6]arene copolymer, in which the first example of pillar[6]arene-functionalized copolymer was synthesized through the reversible addition/fragmentation chain-transfer copolymerization of an acrylate-functionalized pillar[6]arene and methyl acrylate. The resulting supramolecular network exhibits dramatically increased viscosity than the non-cross-linked mixtures and demonstrates a gel-like behavior on macroscale with a transient-network behavior revealed by rheology study. Furthermore, the viscoelastic properties of such supramolecular network can be easily controlled by different external stimuli including redox stimulus and competing host/guest reagents.</abstract><pub>American Chemical Society</pub><doi>10.1021/acs.macromol.5b00889</doi><tpages>7</tpages></addata></record> |
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| ispartof | Macromolecules, 2015-07, Vol.48 (13), p.4403-4409 |
| issn | 0024-9297 1520-5835 1520-5835 |
| language | eng |
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| source | American Chemical Society Journals |
| subjects | aromatic hydrocarbons composite polymers copolymerization rheology viscoelasticity viscosity |
| title | Responsive Gel-like Supramolecular Network Based on Pillar[6]arene–Ferrocenium Recognition Motifs in Polymeric Matrix |
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