Determination of benzylsuccinic acid in gasoline-contaminated groundwater by solid-phase extraction coupled with gas chromatography–mass spectrometry
Benzylsuccinic acid (BSA) and methylbenzylsuccinic acid (methyl-BSA) are unambiguous biotransformation products resulting from anaerobic toluene and xylene biodegradation, respectively. A solid-phase extraction method based on polystyrene–divinylbenzene sorbent was developed for the quantitative BSA...
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| Veröffentlicht in: | Journal of Chromatography A 2002-04, Vol.953 (1), p.215-225 |
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| creator | Reusser, D.E Field, J.A |
| description | Benzylsuccinic acid (BSA) and methylbenzylsuccinic acid (methyl-BSA) are unambiguous biotransformation products resulting from anaerobic toluene and xylene biodegradation, respectively. A solid-phase extraction method based on polystyrene–divinylbenzene sorbent was developed for the quantitative BSA determination in groundwater samples as an alternative to liquid–liquid extraction. Gas chromatography coupled with mass spectrometry was used for separation and detection. The recovery from spiked 1 l groundwater samples was 88 to 100%. The precision of the method, indicated by the relative standard deviation, was ±4% and the method detection limit was 0.2 μg/l. The concentration of BSA and methyl-BSA in groundwater samples from anaerobic BTEX (benzene, toluene, ethylbenzene and xylenes)-contaminated sites ranged from below the detection limit (3 μg/l) to 155 μg/l. |
| doi_str_mv | 10.1016/S0021-9673(02)00107-3 |
| format | Article |
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A solid-phase extraction method based on polystyrene–divinylbenzene sorbent was developed for the quantitative BSA determination in groundwater samples as an alternative to liquid–liquid extraction. Gas chromatography coupled with mass spectrometry was used for separation and detection. The recovery from spiked 1 l groundwater samples was 88 to 100%. The precision of the method, indicated by the relative standard deviation, was ±4% and the method detection limit was 0.2 μg/l. 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A solid-phase extraction method based on polystyrene–divinylbenzene sorbent was developed for the quantitative BSA determination in groundwater samples as an alternative to liquid–liquid extraction. Gas chromatography coupled with mass spectrometry was used for separation and detection. The recovery from spiked 1 l groundwater samples was 88 to 100%. The precision of the method, indicated by the relative standard deviation, was ±4% and the method detection limit was 0.2 μg/l. The concentration of BSA and methyl-BSA in groundwater samples from anaerobic BTEX (benzene, toluene, ethylbenzene and xylenes)-contaminated sites ranged from below the detection limit (3 μg/l) to 155 μg/l.</description><subject>Acidity</subject><subject>Analysis methods</subject><subject>Analytical chemistry</subject><subject>Applied sciences</subject><subject>Benzylsuccinic acid</subject><subject>Chemistry</subject><subject>Chromatographic methods and physical methods associated with chromatography</subject><subject>Ethylbenzene</subject><subject>Exact sciences and technology</subject><subject>Gas chromatographic methods</subject><subject>Gas Chromatography-Mass Spectrometry - methods</subject><subject>Gasoline</subject><subject>Methylation</subject><subject>Natural water pollution</subject><subject>Organic acids</subject><subject>Pollution</subject><subject>Reference Standards</subject><subject>Reproducibility of Results</subject><subject>Succinates - analysis</subject><subject>Toluene</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water treatment and pollution</subject><subject>Xylenes</subject><issn>0021-9673</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkb2O1TAQhVOA2GXhEUBuQFAE_JPfCqHlV1qJAqityWRyr1FiB9thCRXvQMH78SQ4916xJZUtz3fOWOdk2QPBnwkuqucfOZcib6taPeHyKeeC17m6lZ3_ez7L7obwJQ1qXss72ZmQvGxaVZ5nv19RJD8ZC9E4y9zAOrI_1jEsiMYaZICmZ8ayHQQ3Gks5OhvhIKCe7bxbbH-d7p51K9uQPp_3EIjR9-gBD67olnlM9LWJ-82I4d67CaLbeZj365-fvyYIgYWZMKYBRb_ey24PMAa6fzovss9vXn-6fJdffXj7_vLlVY5K1TEf2oLaZoACqRtEJ5uubOsKJMdGViWpAhsUoih4h4J3Q0u8L0VbJh5EB7JVF9njo-_s3deFQtSTCUjjCJbcErTkjaybqkxgeQTRuxA8DXr2ZgK_asH11oI-tKC3uDWX-tCCVkn38LRg6Sbqb1SnChLw6ARAQBgHDxZNuOFUJVolN-7FkaMUxzdDXgc0ZJF641NuunfmP1_5C4owrB8</recordid><startdate>20020412</startdate><enddate>20020412</enddate><creator>Reusser, D.E</creator><creator>Field, J.A</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7T7</scope><scope>7TV</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20020412</creationdate><title>Determination of benzylsuccinic acid in gasoline-contaminated groundwater by solid-phase extraction coupled with gas chromatography–mass spectrometry</title><author>Reusser, D.E ; Field, J.A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-f94e98fa4cebf1b28b5976a20c8265e34c8c11440bc10bf9e0d5195a4ca1ba293</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Acidity</topic><topic>Analysis methods</topic><topic>Analytical chemistry</topic><topic>Applied sciences</topic><topic>Benzylsuccinic acid</topic><topic>Chemistry</topic><topic>Chromatographic methods and physical methods associated with chromatography</topic><topic>Ethylbenzene</topic><topic>Exact sciences and technology</topic><topic>Gas chromatographic methods</topic><topic>Gas Chromatography-Mass Spectrometry - methods</topic><topic>Gasoline</topic><topic>Methylation</topic><topic>Natural water pollution</topic><topic>Organic acids</topic><topic>Pollution</topic><topic>Reference Standards</topic><topic>Reproducibility of Results</topic><topic>Succinates - analysis</topic><topic>Toluene</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water treatment and pollution</topic><topic>Xylenes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reusser, D.E</creatorcontrib><creatorcontrib>Field, J.A</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Journal of Chromatography A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reusser, D.E</au><au>Field, J.A</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of benzylsuccinic acid in gasoline-contaminated groundwater by solid-phase extraction coupled with gas chromatography–mass spectrometry</atitle><jtitle>Journal of Chromatography A</jtitle><addtitle>J Chromatogr A</addtitle><date>2002-04-12</date><risdate>2002</risdate><volume>953</volume><issue>1</issue><spage>215</spage><epage>225</epage><pages>215-225</pages><issn>0021-9673</issn><coden>JOCRAM</coden><abstract>Benzylsuccinic acid (BSA) and methylbenzylsuccinic acid (methyl-BSA) are unambiguous biotransformation products resulting from anaerobic toluene and xylene biodegradation, respectively. A solid-phase extraction method based on polystyrene–divinylbenzene sorbent was developed for the quantitative BSA determination in groundwater samples as an alternative to liquid–liquid extraction. Gas chromatography coupled with mass spectrometry was used for separation and detection. The recovery from spiked 1 l groundwater samples was 88 to 100%. The precision of the method, indicated by the relative standard deviation, was ±4% and the method detection limit was 0.2 μg/l. The concentration of BSA and methyl-BSA in groundwater samples from anaerobic BTEX (benzene, toluene, ethylbenzene and xylenes)-contaminated sites ranged from below the detection limit (3 μg/l) to 155 μg/l.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>12058935</pmid><doi>10.1016/S0021-9673(02)00107-3</doi><tpages>11</tpages></addata></record> |
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| subjects | Acidity Analysis methods Analytical chemistry Applied sciences Benzylsuccinic acid Chemistry Chromatographic methods and physical methods associated with chromatography Ethylbenzene Exact sciences and technology Gas chromatographic methods Gas Chromatography-Mass Spectrometry - methods Gasoline Methylation Natural water pollution Organic acids Pollution Reference Standards Reproducibility of Results Succinates - analysis Toluene Water Pollutants, Chemical - analysis Water treatment and pollution Xylenes |
| title | Determination of benzylsuccinic acid in gasoline-contaminated groundwater by solid-phase extraction coupled with gas chromatography–mass spectrometry |
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