Synthesis and structural characterisation of unprecedented primary N-nitrosamines coordinated to iridium(iv)

The redox chemistry of the N-nitrosamine complexes [IrCl5(RN(H)N[double bond, length as m-dash]O)]2- (R = benzyl or n-butyl) was studied in detail. One-electron oxidations at around 200 mV vs. ferrocene/ferrocenium were reversible in cyclic voltammograms. UV-vis spectroelectrochemistry reveals spect...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (33), p.11445-11454
Hauptverfasser:	Foi, Ana, Salvo, Florencia Di, Doctorovich, Fabio, Huck-Iriart, Cristián, Ramallo-López, José Martín, Dürr, Maximilian, Ivanović-Burmazović, Ivana, Stirnat, Kathrin, Garbe, Simon, Klein, Axel
Format:	Artikel
Sprache:	eng
Schlagworte:	Absorption Alcohols Decomposition Decomposition reactions Fourier transforms Iridium Mass spectrometry Nitrosamine NMR spectroscopy Organic chemistry
Online-Zugang:	Volltext
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