Factor analysis of transesterification reaction of waste oil for biodiesel production
In the present paper a factor analysis is presented for the enzymatic transesterification of waste oil for biodiesel production. The experimental data on batch reactor evidence two key variables: enzyme loading and mixing conditions. These variables were subjected to a factor analysis and their comb...
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Veröffentlicht in: | Bioresource technology 2009-11, Vol.100 (21), p.5126-5131 |
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description | In the present paper a factor analysis is presented for the enzymatic transesterification of waste oil for biodiesel production. The experimental data on batch reactor evidence two key variables: enzyme loading and mixing conditions. These variables were subjected to a factor analysis and their combined effect on the reaction performance was determined. Response surface methodology (RSM) was used based on a linear first order model (steepest ascent method) and on a second order one in proximity of the optimal solution. The result was a model able to predict reaction performance within the range of mixing rates and enzyme amount considered for model formulation and outside of it, as shown in the final validation. Best performances were obtained at high stirring and high enzyme loading. |
doi_str_mv | 10.1016/j.biortech.2009.05.027 |
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The experimental data on batch reactor evidence two key variables: enzyme loading and mixing conditions. These variables were subjected to a factor analysis and their combined effect on the reaction performance was determined. Response surface methodology (RSM) was used based on a linear first order model (steepest ascent method) and on a second order one in proximity of the optimal solution. The result was a model able to predict reaction performance within the range of mixing rates and enzyme amount considered for model formulation and outside of it, as shown in the final validation. Best performances were obtained at high stirring and high enzyme loading.</description><identifier>ISSN: 0960-8524</identifier><identifier>EISSN: 1873-2976</identifier><identifier>DOI: 10.1016/j.biortech.2009.05.027</identifier><identifier>PMID: 19500974</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; batch fermentation ; Biodiesel ; Bioelectric Energy Sources ; Biofuel production ; Biological and medical sciences ; Biotechnology ; biotransformation ; Energy ; Environmental pollutant ; enzymatic hydrolysis ; Esterification ; Exact sciences and technology ; fatty acid esters ; food processing wastes ; Fundamental and applied biological sciences. Psychology ; hulls ; Immobilization of enzymes and other molecules ; Immobilization techniques ; Immobilized enzymes ; Industrial applications and implications. Economical aspects ; linear models ; Lipase ; mathematical models ; Methods. Procedures. Technologies ; Models, Chemical ; olive oil ; olives ; Plant Oils - chemistry ; Pollution ; renewable energy sources ; Reproducibility of Results ; response surface methodology ; Surface Properties ; Time Factors ; transesterification ; triacylglycerol lipase ; vegetable oil ; Waste conversion ; Waste Products - analysis ; Wastes</subject><ispartof>Bioresource technology, 2009-11, Vol.100 (21), p.5126-5131</ispartof><rights>2009 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c451t-4b6afa6d4852c8cfed33c91f7de029f85c23188860f89e91dd2fd9e7fee334503</citedby><cites>FETCH-LOGICAL-c451t-4b6afa6d4852c8cfed33c91f7de029f85c23188860f89e91dd2fd9e7fee334503</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0960852409005677$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=21782139$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19500974$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>De Paola, M.G.</creatorcontrib><creatorcontrib>Ricca, E.</creatorcontrib><creatorcontrib>Calabrò, V.</creatorcontrib><creatorcontrib>Curcio, S.</creatorcontrib><creatorcontrib>Iorio, G.</creatorcontrib><title>Factor analysis of transesterification reaction of waste oil for biodiesel production</title><title>Bioresource technology</title><addtitle>Bioresour Technol</addtitle><description>In the present paper a factor analysis is presented for the enzymatic transesterification of waste oil for biodiesel production. The experimental data on batch reactor evidence two key variables: enzyme loading and mixing conditions. These variables were subjected to a factor analysis and their combined effect on the reaction performance was determined. Response surface methodology (RSM) was used based on a linear first order model (steepest ascent method) and on a second order one in proximity of the optimal solution. The result was a model able to predict reaction performance within the range of mixing rates and enzyme amount considered for model formulation and outside of it, as shown in the final validation. Best performances were obtained at high stirring and high enzyme loading.</description><subject>Applied sciences</subject><subject>batch fermentation</subject><subject>Biodiesel</subject><subject>Bioelectric Energy Sources</subject><subject>Biofuel production</subject><subject>Biological and medical sciences</subject><subject>Biotechnology</subject><subject>biotransformation</subject><subject>Energy</subject><subject>Environmental pollutant</subject><subject>enzymatic hydrolysis</subject><subject>Esterification</subject><subject>Exact sciences and technology</subject><subject>fatty acid esters</subject><subject>food processing wastes</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>hulls</subject><subject>Immobilization of enzymes and other molecules</subject><subject>Immobilization techniques</subject><subject>Immobilized enzymes</subject><subject>Industrial applications and implications. Economical aspects</subject><subject>linear models</subject><subject>Lipase</subject><subject>mathematical models</subject><subject>Methods. Procedures. Technologies</subject><subject>Models, Chemical</subject><subject>olive oil</subject><subject>olives</subject><subject>Plant Oils - chemistry</subject><subject>Pollution</subject><subject>renewable energy sources</subject><subject>Reproducibility of Results</subject><subject>response surface methodology</subject><subject>Surface Properties</subject><subject>Time Factors</subject><subject>transesterification</subject><subject>triacylglycerol lipase</subject><subject>vegetable oil</subject><subject>Waste conversion</subject><subject>Waste Products - analysis</subject><subject>Wastes</subject><issn>0960-8524</issn><issn>1873-2976</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEuPFCEUhYnROO3oXxhro7sqL1DFY6eZ-EomcaGzJjRclE51MUK1Zv69t-1Wl64g4Tuck4-xKw4DB65e7YZtLnXF8G0QAHaAaQChH7ANN1r2wmr1kG3AKujNJMYL9qS1HQBIrsVjdsHtRCE9btjtOx_WUju_-Pm-5daV1K3VLw3bijWnHPyay9JVJO54ofefnt66kucuUZJ2xIwN5-6ulnj4TT1lj5KfGz47n5fU8_bL9Yf-5tP7j9dvbvowTnztx63yyas40sZgQsIoZbA86YggbDJTEJIbYxQkY9HyGEWKFnVClHKcQF6yl6d_qfr7gSa7fW4B59kvWA7NCdBKWXsE1QkMtbRWMbm7mve-3jsO7ijU7dwfoe4o1MHkSCgFr84Nh-0e47_Y2SABL86Ab8HPidyF3P5ygmsjuLTEPT9xyRfnv1Zibj8L4JLKJwOWE_H6RCAZ-5GxuhYyLgFjrhhWF0v-39pfLNOiWQ</recordid><startdate>20091101</startdate><enddate>20091101</enddate><creator>De Paola, M.G.</creator><creator>Ricca, E.</creator><creator>Calabrò, V.</creator><creator>Curcio, S.</creator><creator>Iorio, G.</creator><general>Elsevier Ltd</general><general>[New York, NY]: Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope></search><sort><creationdate>20091101</creationdate><title>Factor analysis of transesterification reaction of waste oil for biodiesel production</title><author>De Paola, M.G. ; Ricca, E. ; Calabrò, V. ; Curcio, S. ; Iorio, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c451t-4b6afa6d4852c8cfed33c91f7de029f85c23188860f89e91dd2fd9e7fee334503</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Applied sciences</topic><topic>batch fermentation</topic><topic>Biodiesel</topic><topic>Bioelectric Energy Sources</topic><topic>Biofuel production</topic><topic>Biological and medical sciences</topic><topic>Biotechnology</topic><topic>biotransformation</topic><topic>Energy</topic><topic>Environmental pollutant</topic><topic>enzymatic hydrolysis</topic><topic>Esterification</topic><topic>Exact sciences and technology</topic><topic>fatty acid esters</topic><topic>food processing wastes</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>hulls</topic><topic>Immobilization of enzymes and other molecules</topic><topic>Immobilization techniques</topic><topic>Immobilized enzymes</topic><topic>Industrial applications and implications. Economical aspects</topic><topic>linear models</topic><topic>Lipase</topic><topic>mathematical models</topic><topic>Methods. Procedures. Technologies</topic><topic>Models, Chemical</topic><topic>olive oil</topic><topic>olives</topic><topic>Plant Oils - chemistry</topic><topic>Pollution</topic><topic>renewable energy sources</topic><topic>Reproducibility of Results</topic><topic>response surface methodology</topic><topic>Surface Properties</topic><topic>Time Factors</topic><topic>transesterification</topic><topic>triacylglycerol lipase</topic><topic>vegetable oil</topic><topic>Waste conversion</topic><topic>Waste Products - analysis</topic><topic>Wastes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>De Paola, M.G.</creatorcontrib><creatorcontrib>Ricca, E.</creatorcontrib><creatorcontrib>Calabrò, V.</creatorcontrib><creatorcontrib>Curcio, S.</creatorcontrib><creatorcontrib>Iorio, G.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Bioresource technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>De Paola, M.G.</au><au>Ricca, E.</au><au>Calabrò, V.</au><au>Curcio, S.</au><au>Iorio, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Factor analysis of transesterification reaction of waste oil for biodiesel production</atitle><jtitle>Bioresource technology</jtitle><addtitle>Bioresour Technol</addtitle><date>2009-11-01</date><risdate>2009</risdate><volume>100</volume><issue>21</issue><spage>5126</spage><epage>5131</epage><pages>5126-5131</pages><issn>0960-8524</issn><eissn>1873-2976</eissn><abstract>In the present paper a factor analysis is presented for the enzymatic transesterification of waste oil for biodiesel production. The experimental data on batch reactor evidence two key variables: enzyme loading and mixing conditions. These variables were subjected to a factor analysis and their combined effect on the reaction performance was determined. Response surface methodology (RSM) was used based on a linear first order model (steepest ascent method) and on a second order one in proximity of the optimal solution. The result was a model able to predict reaction performance within the range of mixing rates and enzyme amount considered for model formulation and outside of it, as shown in the final validation. Best performances were obtained at high stirring and high enzyme loading.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>19500974</pmid><doi>10.1016/j.biortech.2009.05.027</doi><tpages>6</tpages></addata></record> |
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subjects | Applied sciences batch fermentation Biodiesel Bioelectric Energy Sources Biofuel production Biological and medical sciences Biotechnology biotransformation Energy Environmental pollutant enzymatic hydrolysis Esterification Exact sciences and technology fatty acid esters food processing wastes Fundamental and applied biological sciences. Psychology hulls Immobilization of enzymes and other molecules Immobilization techniques Immobilized enzymes Industrial applications and implications. Economical aspects linear models Lipase mathematical models Methods. Procedures. Technologies Models, Chemical olive oil olives Plant Oils - chemistry Pollution renewable energy sources Reproducibility of Results response surface methodology Surface Properties Time Factors transesterification triacylglycerol lipase vegetable oil Waste conversion Waste Products - analysis Wastes |
title | Factor analysis of transesterification reaction of waste oil for biodiesel production |
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