Experimental and computational studies on H2O-promoted, Rh-catalyzed transient-ligand-free ortho-C(sp2)–H amidation of benzaldehydes with dioxazolones

An efficient and convenient ligand-free, rhodium-catalyzed ortho-C(sp2)–H amidation of benzaldehydes with dioxazolones using H2O as the key promoter is described. Using this protocol, a wide range of benzaldehyde substrates were selectively amidated in good to excellent yields with broad functional...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018, Vol.54 (64), p.8889-8892
Hauptverfasser:	Ding, Jun, Jiang, Wei, He-Yuan, Bai, Tong-Mei, Ding, Gao, Dafang, Bao, Xiaoguang, Shu-Yu, Zhang
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzaldehyde Catalysis Computation Functional groups Hydrogen bonds Ligands Rhodium Substrates
Online-Zugang:	Volltext
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