Field-induced single-molecule magnet behavior in ideal trigonal antiprismatic cobalt(ii) complexes: precise geometrical control by a hydrogen-bonded rigid metalloligand

A new cobalt(ii) complex bearing a pair of cobalt(iii) tris-chelate complexes as metalloligands was prepared. The CoII ion possesses an ideal trigonal antiprismatic geometry because of the intermolecular hydrogen-bonds between the metalloligands via counter anions. This complex exhibits slow magneti...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018, Vol.54 (64), p.8869-8872
Hauptverfasser:	Mitsuhashi, Ryoji, Pedersen, Kasper S, Ueda, Takaaki, Suzuki, Takayoshi, Bendix, Jesper, Mikuriya, Masahiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Chelates Cobalt Coordination compounds Hydrogen bonding Hydrogen bonds Magnetic induction Magnetic relaxation
Online-Zugang:	Volltext
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