Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes
In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl- N , N ′-bis( p -tolyl)malonimidate and 1,3-bis(dimethylamino)- N , N' -bis( p -tolyl)propanediimidate. Their corresponding rhodium( i ) dicarbonyl, dimethylaluminium, and bis-ligated...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018-07, Vol.47 (3), p.1195-125 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Land, Michael A Huo, Bright Robertson, Katherine N Ylijoki, Kai E. O Lee, Peter T. K Areephong, Jetsuda Vidovi, Dragoslav Clyburne, Jason A. C |
| description | In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-
N
,
N
′-bis(
p
-tolyl)malonimidate and 1,3-bis(dimethylamino)-
N
,
N'
-bis(
p
-tolyl)propanediimidate. Their corresponding rhodium(
i
) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic
N
,
N'
-chelating ligand
nacnac
.
Two new anionic ligands
L
and their metal complexes Zn
L
2
, (CH
3
)
2
Al
L
, and
L
Rh(CO)
2
(shown) have been prepared and fully characterized. |
| doi_str_mv | 10.1039/c8dt01875h |
| format | Article |
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N
,
N
′-bis(
p
-tolyl)malonimidate and 1,3-bis(dimethylamino)-
N
,
N'
-bis(
p
-tolyl)propanediimidate. Their corresponding rhodium(
i
) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic
N
,
N'
-chelating ligand
nacnac
.
Two new anionic ligands
L
and their metal complexes Zn
L
2
, (CH
3
)
2
Al
L
, and
L
Rh(CO)
2
(shown) have been prepared and fully characterized.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt01875h</identifier><identifier>PMID: 30014057</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chelation ; Coordination compounds ; Crystal structure ; Ligands ; Rhodium</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018-07, Vol.47 (3), p.1195-125</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-d6a39cc14333d93a37e9640af5822fc2cc72a8800406b4235ce6e6dafe73850d3</citedby><cites>FETCH-LOGICAL-c337t-d6a39cc14333d93a37e9640af5822fc2cc72a8800406b4235ce6e6dafe73850d3</cites><orcidid>0000-0001-5861-242X ; 0000-0003-4269-3995 ; 0000-0002-0722-4862 ; 0000-0002-5602-8059</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30014057$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Land, Michael A</creatorcontrib><creatorcontrib>Huo, Bright</creatorcontrib><creatorcontrib>Robertson, Katherine N</creatorcontrib><creatorcontrib>Ylijoki, Kai E. O</creatorcontrib><creatorcontrib>Lee, Peter T. K</creatorcontrib><creatorcontrib>Areephong, Jetsuda</creatorcontrib><creatorcontrib>Vidovi, Dragoslav</creatorcontrib><creatorcontrib>Clyburne, Jason A. C</creatorcontrib><title>Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-
N
,
N
′-bis(
p
-tolyl)malonimidate and 1,3-bis(dimethylamino)-
N
,
N'
-bis(
p
-tolyl)propanediimidate. Their corresponding rhodium(
i
) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic
N
,
N'
-chelating ligand
nacnac
.
Two new anionic ligands
L
and their metal complexes Zn
L
2
, (CH
3
)
2
Al
L
, and
L
Rh(CO)
2
(shown) have been prepared and fully characterized.</description><subject>Chelation</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>Ligands</subject><subject>Rhodium</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkU1P3DAQhq0KBHTh0nsrS71U1YaO7SR2jmjLl4TEZXuOvPaka5rEi-0g9pfwd8nu0kXiNDOa550PvYR8YXDOQFS_jLIJmJLF8hM5YbmUWcVFfrDPeXlMPsf4AMA5FPyIHAsAlkMhT8jLzPtgXa-T8_2UBtQmuSeX1lOqe0tjCoNJQ9AtXQW_wpAcRuobii2aFHyfBWeWFNPSP6-zrcS6bizXre5c77M4LGJyaUhoKZuKzLp_mFy3WYi0dX9HRdzK0hJdoMZ3qxafMZ6Sw0a3Ec_e4oT8ubqcz26yu_vr29nFXWaEkCmzpRaVMSwXQthKaCGxKnPQTaE4bww3RnKtFEAO5SLnojBYYml1g1KoAqyYkB-7ueN7jwPGVHcuGmxb3aMfYs1BskICV_mIfv-APvgh9ON1G6qqSlWyDfVzR5ngYwzY1KvgOh3WNYN6Y1c9U7_nW7tuRvjb28hh0aHdo__9GYGvOyBEs----y1eAS3KnHc</recordid><startdate>20180731</startdate><enddate>20180731</enddate><creator>Land, Michael A</creator><creator>Huo, Bright</creator><creator>Robertson, Katherine N</creator><creator>Ylijoki, Kai E. O</creator><creator>Lee, Peter T. K</creator><creator>Areephong, Jetsuda</creator><creator>Vidovi, Dragoslav</creator><creator>Clyburne, Jason A. C</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-5861-242X</orcidid><orcidid>https://orcid.org/0000-0003-4269-3995</orcidid><orcidid>https://orcid.org/0000-0002-0722-4862</orcidid><orcidid>https://orcid.org/0000-0002-5602-8059</orcidid></search><sort><creationdate>20180731</creationdate><title>Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes</title><author>Land, Michael A ; Huo, Bright ; Robertson, Katherine N ; Ylijoki, Kai E. O ; Lee, Peter T. K ; Areephong, Jetsuda ; Vidovi, Dragoslav ; Clyburne, Jason A. C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-d6a39cc14333d93a37e9640af5822fc2cc72a8800406b4235ce6e6dafe73850d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chelation</topic><topic>Coordination compounds</topic><topic>Crystal structure</topic><topic>Ligands</topic><topic>Rhodium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Land, Michael A</creatorcontrib><creatorcontrib>Huo, Bright</creatorcontrib><creatorcontrib>Robertson, Katherine N</creatorcontrib><creatorcontrib>Ylijoki, Kai E. O</creatorcontrib><creatorcontrib>Lee, Peter T. K</creatorcontrib><creatorcontrib>Areephong, Jetsuda</creatorcontrib><creatorcontrib>Vidovi, Dragoslav</creatorcontrib><creatorcontrib>Clyburne, Jason A. C</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Land, Michael A</au><au>Huo, Bright</au><au>Robertson, Katherine N</au><au>Ylijoki, Kai E. O</au><au>Lee, Peter T. K</au><au>Areephong, Jetsuda</au><au>Vidovi, Dragoslav</au><au>Clyburne, Jason A. C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018-07-31</date><risdate>2018</risdate><volume>47</volume><issue>3</issue><spage>1195</spage><epage>125</epage><pages>1195-125</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>In this paper we describe the synthesis, characterization, and X-ray crystal structures of two ligands, diethyl-
N
,
N
′-bis(
p
-tolyl)malonimidate and 1,3-bis(dimethylamino)-
N
,
N'
-bis(
p
-tolyl)propanediimidate. Their corresponding rhodium(
i
) dicarbonyl, dimethylaluminium, and bis-ligated zinc complexes have also been prepared and characterized. The donor properties of the ligands have been studied and have been compared to those of the traditional anionic
N
,
N'
-chelating ligand
nacnac
.
Two new anionic ligands
L
and their metal complexes Zn
L
2
, (CH
3
)
2
Al
L
, and
L
Rh(CO)
2
(shown) have been prepared and fully characterized.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30014057</pmid><doi>10.1039/c8dt01875h</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-5861-242X</orcidid><orcidid>https://orcid.org/0000-0003-4269-3995</orcidid><orcidid>https://orcid.org/0000-0002-0722-4862</orcidid><orcidid>https://orcid.org/0000-0002-5602-8059</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018-07, Vol.47 (3), p.1195-125 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2071570284 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chelation Coordination compounds Crystal structure Ligands Rhodium |
| title | Coordination, reactivity, and structural properties of electron-rich ethoxy- and dimethylamino-substituted 1,3-diketiminate ligands and their complexes |
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