Magnesium Stung by Nonclassical Scorpionate Ligands: Synthesis and Cone‐Angle Calculations

A series of tris(pyrazolyl)alkane (RCTp) scorpionate ligands of the type RCTp3‐R′ (R=Me, nBu, SiMe3; R′=H, Me, Ph, iPr, tBu) were synthesized and their ability to coordinate methylmagnesium moieties was examined. The reaction of Mg(AlMe4)2 with neutral proligands HCTp3‐Ph or Me3SiCTp3‐Me, containing...

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Veröffentlicht in:	Chemistry : a European journal 2018-09, Vol.24 (53), p.14254-14268
Hauptverfasser:	Stuhl, Christoph, Maichle‐Mössmer, Cäcilia, Anwander, Reiner
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkanes Chemical synthesis Chemistry Coordination compounds coordination modes Ion pairs ligand effects Ligands Magnesium Mathematical analysis scorpionate ligands substituent effects
Online-Zugang:	Volltext
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