Homoleptic Trifluoromethyl Derivatives of AgI and AgIII

The homoleptic silver(I) compound [PPh4][CF3AgCF3] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4][Ag(CF3)4] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their structural and spectroscopic properties have been experimental...

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Veröffentlicht in:	Chemistry : a European journal 2018-09, Vol.24 (50), p.13098-13101
Hauptverfasser:	Joven‐Sancho, Daniel, Baya, Miguel, Martín, Antonio, Menjón, Babil
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electronic structure highest oxidation states homoleptic ligand-field inversion Ligands organosilver Silver silver(III)
Online-Zugang:	Volltext
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