The role of sodium carbonate in PAM coagulation-flocculation for oil acidized wastewater treatment

The pH value of oil acidized wastewater is relatively low (pH = 6.1), which seriously affects the flocculation of polyacrylamide (PAM). NaOH was used to adjust the pH value, but the maximum was only 7.5. The regulation was limited as the Ca in aqueous phase up to 1,350 mg L consumed OH . A novel for...

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Veröffentlicht in:Water science and technology 2018-06, Vol.77 (11-12), p.2677-2686
Hauptverfasser: Qin, Jinyi, Wang, Hainan, Qin, Chuan, Meng, Hailong, Qu, Wengang, Qian, Hui
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container_issue 11-12
container_start_page 2677
container_title Water science and technology
container_volume 77
creator Qin, Jinyi
Wang, Hainan
Qin, Chuan
Meng, Hailong
Qu, Wengang
Qian, Hui
description The pH value of oil acidized wastewater is relatively low (pH = 6.1), which seriously affects the flocculation of polyacrylamide (PAM). NaOH was used to adjust the pH value, but the maximum was only 7.5. The regulation was limited as the Ca in aqueous phase up to 1,350 mg L consumed OH . A novel formulation of Na CO + PAM was proposed to form CaCO floc core to facilitate PAM coagulation. When the concentration was above 400 mg L , the PAM precipitation tended to be maximum, followed by NaOH adjustment of pH to 8.0 that could enhance PAM flocculation successively. The sewage sludge (SS) remained and residue oil reduced to 25 mg L and 34mg L respectively. The analysis of the species and composition of fatty acids indicated that the coagulation-flocculation selectively effected the sedimentation of saturated fatty acids (SAT). This provides a new idea for recovery of high value-added residual oil. The optimal additive of Na CO is expected as promising coagulant aid to improve the PAM coagulation-flocculation of oil acidized wastewater.
doi_str_mv 10.2166/wst.2018.224
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NaOH was used to adjust the pH value, but the maximum was only 7.5. The regulation was limited as the Ca in aqueous phase up to 1,350 mg L consumed OH . A novel formulation of Na CO + PAM was proposed to form CaCO floc core to facilitate PAM coagulation. When the concentration was above 400 mg L , the PAM precipitation tended to be maximum, followed by NaOH adjustment of pH to 8.0 that could enhance PAM flocculation successively. The sewage sludge (SS) remained and residue oil reduced to 25 mg L and 34mg L respectively. The analysis of the species and composition of fatty acids indicated that the coagulation-flocculation selectively effected the sedimentation of saturated fatty acids (SAT). This provides a new idea for recovery of high value-added residual oil. 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identifier ISSN: 0273-1223
ispartof Water science and technology, 2018-06, Vol.77 (11-12), p.2677-2686
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1996-9732
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subjects Abandoned mines
Additives
Calcium carbonate
Calcium ions
Carbonates
Chloride
Coagulants
Coagulation
Composition
Experiments
Fatty acids
Flocculation
Oil
Oil recovery
Petroleum
pH effects
Polymers
Sedimentation
Sewage
Sewage sludge
Sludge
Sodium
Sodium carbonate
Sodium hydroxide
Soil contamination
Wastewater
Wastewater treatment
Water treatment
title The role of sodium carbonate in PAM coagulation-flocculation for oil acidized wastewater treatment
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