Switchable Selectivity in the Pd-Catalyzed Alkylative Cross-Coupling of Esters

The Pd-catalyzed cross-coupling of phenyl esters and alkyl boranes is disclosed. Two reaction modes are rendered accessible in a selective fashion by interchange of the catalyst. With a Pd–NHC system, alkyl ketones can be prepared in good yields via a Suzuki–Miyaura reaction proceeding by activation...

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Veröffentlicht in:	Organic letters 2018-07, Vol.20 (13), p.4094-4098
Hauptverfasser:	Masson-Makdissi, Jeanne, Vandavasi, Jaya Kishore, Newman, Stephen G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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