Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C-H borylation catalysts

While the dearomatization of indoles by carbon-boron bond forming reactions is new and quite promising, they are so far mainly metal-catalyzed. Here, we establish the use of metal-free catalysts in promoting such reactions in an atom-efficient way. The generated ambiphilic aminoborane catalyst (1-Pi...

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Veröffentlicht in:	Chemical science (Cambridge) 2018-06, Vol.9 (22), p.5057-5063
Hauptverfasser:	Jayaraman, Arumugam, Misal Castro, Luis C, Desrosiers, Vincent, Fontaine, Frédéric-Georges
Format:	Artikel
Sprache:	eng
Schlagworte:	Boranes Boron Catalysis Catalysts Indoles
Online-Zugang:	Volltext
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