Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage
Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. In this work, a freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐...
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Veröffentlicht in: | Chemistry : a European journal 2018-09, Vol.24 (51), p.13535-13539 |
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creator | Gao, Shuang Chen, Gang Dall'Agnese, Yohan Wei, Yingjin Gao, Zhongmin Gao, Yu |
description | Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. In this work, a freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. MnS nanoparticles have a size of about 5 nm and the particles are evenly distributed in the carbon nanofibers. Carbon nanofibers act as electronic conductors and buffer the volume change, while MnS nanoparticles react through rapid electrochemical reaction. As a Li‐ion battery anode, this hybrid electrode exhibits specific capacities from 240 mAh g−1 at a high current density of 5 A g−1, up to 600 mAh g−1 at 200 mA g−1.
Hybrid theory: A freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. Good rate performances were observed, attributed to an open 3D architecture. |
doi_str_mv | 10.1002/chem.201801979 |
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Hybrid theory: A freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. Good rate performances were observed, attributed to an open 3D architecture.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201801979</identifier><identifier>PMID: 29904945</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Batteries ; Battery cycles ; Carbon ; Carbon fibers ; Chemistry ; Conductors ; Electrochemistry ; Electrodes ; Energy storage ; flexible ; Hybrids ; Lithium ; lithium-ion battery ; manganese sulfide ; Nanofibers ; Nanoparticles ; nanostructures ; Sodium ; sodium-ion battery ; Sulfides</subject><ispartof>Chemistry : a European journal, 2018-09, Vol.24 (51), p.13535-13539</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5209-aa8721ec91c35c0ccdddccbc6aea84007897c679aa17369e3dddeb3fcb2509c83</citedby><cites>FETCH-LOGICAL-c5209-aa8721ec91c35c0ccdddccbc6aea84007897c679aa17369e3dddeb3fcb2509c83</cites><orcidid>0000-0002-8158-9798</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201801979$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201801979$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29904945$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Gao, Shuang</creatorcontrib><creatorcontrib>Chen, Gang</creatorcontrib><creatorcontrib>Dall'Agnese, Yohan</creatorcontrib><creatorcontrib>Wei, Yingjin</creatorcontrib><creatorcontrib>Gao, Zhongmin</creatorcontrib><creatorcontrib>Gao, Yu</creatorcontrib><title>Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. In this work, a freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. MnS nanoparticles have a size of about 5 nm and the particles are evenly distributed in the carbon nanofibers. Carbon nanofibers act as electronic conductors and buffer the volume change, while MnS nanoparticles react through rapid electrochemical reaction. As a Li‐ion battery anode, this hybrid electrode exhibits specific capacities from 240 mAh g−1 at a high current density of 5 A g−1, up to 600 mAh g−1 at 200 mA g−1.
Hybrid theory: A freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. Good rate performances were observed, attributed to an open 3D architecture.</description><subject>Batteries</subject><subject>Battery cycles</subject><subject>Carbon</subject><subject>Carbon fibers</subject><subject>Chemistry</subject><subject>Conductors</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Energy storage</subject><subject>flexible</subject><subject>Hybrids</subject><subject>Lithium</subject><subject>lithium-ion battery</subject><subject>manganese sulfide</subject><subject>Nanofibers</subject><subject>Nanoparticles</subject><subject>nanostructures</subject><subject>Sodium</subject><subject>sodium-ion battery</subject><subject>Sulfides</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOAjEUQBujEUS3Ls0kbtwM3rZ0Zro0BMQE4gJdN53ORYbMA1smyo5PMPEP-RJLUEncuGrSe3p6cwi5pNClAOzWzLHsMqAJUBnLI9KmgtGQx5E4Jm2QvTiMBJctcubcAgBkxPkpaTEpoSd7ok2ehwW-52mBwaSabjeffW3TugqGeYo2GK1Tm2cumNU2GOered6U283Hg5_rKgumdXa4GFRoX9bBdFVb_YLn5GSmC4cX32fH_zN46o_C8eP9Q_9uHBrBQIZaJzGjaCQ1XBgwJssyY1ITadRJDyBOZGyiWGpNYx5J5H6OKZ-ZlAmQJuEdcrP3Lm392qBbqTJ3BotCV1g3TjEQkfcIyj16_Qdd1I2t_HaKUWCc-nDgqe6eMrZ2zuJMLW1eartWFNQuuNoFV7_B_YOrb22Tlpj94j-FPSD3wFte4PofneqPBpOD_AvAA48h</recordid><startdate>20180912</startdate><enddate>20180912</enddate><creator>Gao, Shuang</creator><creator>Chen, Gang</creator><creator>Dall'Agnese, Yohan</creator><creator>Wei, Yingjin</creator><creator>Gao, Zhongmin</creator><creator>Gao, Yu</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-8158-9798</orcidid></search><sort><creationdate>20180912</creationdate><title>Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage</title><author>Gao, Shuang ; Chen, Gang ; Dall'Agnese, Yohan ; Wei, Yingjin ; Gao, Zhongmin ; Gao, Yu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5209-aa8721ec91c35c0ccdddccbc6aea84007897c679aa17369e3dddeb3fcb2509c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Batteries</topic><topic>Battery cycles</topic><topic>Carbon</topic><topic>Carbon fibers</topic><topic>Chemistry</topic><topic>Conductors</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Energy storage</topic><topic>flexible</topic><topic>Hybrids</topic><topic>Lithium</topic><topic>lithium-ion battery</topic><topic>manganese sulfide</topic><topic>Nanofibers</topic><topic>Nanoparticles</topic><topic>nanostructures</topic><topic>Sodium</topic><topic>sodium-ion battery</topic><topic>Sulfides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gao, Shuang</creatorcontrib><creatorcontrib>Chen, Gang</creatorcontrib><creatorcontrib>Dall'Agnese, Yohan</creatorcontrib><creatorcontrib>Wei, Yingjin</creatorcontrib><creatorcontrib>Gao, Zhongmin</creatorcontrib><creatorcontrib>Gao, Yu</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gao, Shuang</au><au>Chen, Gang</au><au>Dall'Agnese, Yohan</au><au>Wei, Yingjin</au><au>Gao, Zhongmin</au><au>Gao, Yu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2018-09-12</date><risdate>2018</risdate><volume>24</volume><issue>51</issue><spage>13535</spage><epage>13539</epage><pages>13535-13539</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. 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subjects | Batteries Battery cycles Carbon Carbon fibers Chemistry Conductors Electrochemistry Electrodes Energy storage flexible Hybrids Lithium lithium-ion battery manganese sulfide Nanofibers Nanoparticles nanostructures Sodium sodium-ion battery Sulfides |
title | Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage |
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