Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage

Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. In this work, a freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐...

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Veröffentlicht in:Chemistry : a European journal 2018-09, Vol.24 (51), p.13535-13539
Hauptverfasser: Gao, Shuang, Chen, Gang, Dall'Agnese, Yohan, Wei, Yingjin, Gao, Zhongmin, Gao, Yu
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container_end_page 13539
container_issue 51
container_start_page 13535
container_title Chemistry : a European journal
container_volume 24
creator Gao, Shuang
Chen, Gang
Dall'Agnese, Yohan
Wei, Yingjin
Gao, Zhongmin
Gao, Yu
description Nanostructures can improve battery capacity and cycle life, especially with sulfide electrodes. In this work, a freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. MnS nanoparticles have a size of about 5 nm and the particles are evenly distributed in the carbon nanofibers. Carbon nanofibers act as electronic conductors and buffer the volume change, while MnS nanoparticles react through rapid electrochemical reaction. As a Li‐ion battery anode, this hybrid electrode exhibits specific capacities from 240 mAh g−1 at a high current density of 5 A g−1, up to 600 mAh g−1 at 200 mA g−1. Hybrid theory: A freestanding flexible electrode, consisting of MnS nanoparticles embedded onto carbon nanofibers, was prepared by electrospinning. The produced hybrid was used as an electrode for lithium‐ion and sodium‐ion batteries. Good rate performances were observed, attributed to an open 3D architecture.
doi_str_mv 10.1002/chem.201801979
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subjects Batteries
Battery cycles
Carbon
Carbon fibers
Chemistry
Conductors
Electrochemistry
Electrodes
Energy storage
flexible
Hybrids
Lithium
lithium-ion battery
manganese sulfide
Nanofibers
Nanoparticles
nanostructures
Sodium
sodium-ion battery
Sulfides
title Flexible MnS–Carbon Fiber Hybrids for Lithium‐Ion and Sodium‐Ion Energy Storage
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