Atmospheric Chemistry of 2-ethoxy-3,3,4,4,5-pentafluorotetrahydro-2,5-bis[1,2,2,2-tetrafluoro- 1-(trifluoromethyl)ethyl]-furan:  Kinetics, Mechanisms, and Products of Cl Atom and OH Radical Initiated Oxidation

Smog chamber/FTIR techniques were used to study the atmospheric chemistry of the title compound which we refer to as R fOC2H5. Rate constants of k(Cl + R fOC2H5) = (2.70 ± 0.36) × 10-12, k(OH + R fOC2H5) = (5.93 ± 0.85) × 10-14, and k(Cl + R fOCHO) = (1.34 ± 0.20) × 10-14 cm3 molecule-1 s-1 were mea...

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Veröffentlicht in:	Environmental science & technology 2007-11, Vol.41 (21), p.7389-7395
Hauptverfasser:	Javadi, M. S, Nielsen, O. J, Wallington, T. J, Hurley, M. D, Owens, J. G
Format:	Artikel
Sprache:	eng
Schlagworte:	Air Pollutants - chemistry Atmospheric chemistry Chlorine - chemistry Environment Environmental impact Environmental monitoring Environmental science Furans - chemistry Global warming Hydrocarbons, Fluorinated - chemistry Hydroxyl Radical - chemistry Kinetics Molecules Oxidation Oxidation-Reduction
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