The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers
New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by vary...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (25), p.8356-8363 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 47 |
| creator | Tingare, Yogesh S Akula, Suri Babu Shen, Ming-Tai Su, Chaochin Ho, Shih-Yu Tsai, Sheng-Han Lin, Ya-Fen Li, Wen-Ren |
| description | New heteroleptic Ru(ii) complexes consisting of pyridylimine as an ancillary ligand were synthesized and characterized for applications in dye sensitized solar cells. Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. The effect of the difference in the configurations of these complexes on their device performances was studied and the sensitizer with a trans arrangement around the metal showed a higher overall conversion efficiency (η) of 7.27% than that of the cis configured complex (η = 2.04%). |
| doi_str_mv | 10.1039/c8dt01131a |
| format | Article |
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Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. 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Complexes with cis and trans configurations around the central ruthenium metal were obtained using simple synthetic protocols by varying the substituents on the pyridylimine ligands. The geometries of these complexes were confirmed by single crystal X-ray analysis. 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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018, Vol.47 (25), p.8356-8363 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Configurations Dye-sensitized solar cells Ligands Photovoltaic cells Ruthenium compounds Single crystals X ray analysis |
| title | The effect of cis-trans configurational difference on the performance of pyridylimine-based ruthenium sensitizers |
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