New Frontiers in Electron Beam–Driven Chemistry in and around Graphene

Modern aberration corrected transmission electron microscopes offer the potential for electron beam sensitive materials, such as graphene, to be examined with low energy electrons to minimize, and even avoid, damage while still affording atomic resolution, and thus providing excellent characterization. Here in this review, the exploits in which the electron beam interactions, which are often considered negative, are explored to usefully drive a wealth of chemistry in and around graphene, importantly, with no other external stimuli. After introducing the technique, this review covers carbon phase reactions between amorphous carbon, graphene, fullerenes, carbon chains, and carbon nanotubes. It then explores different studies with clusters and nanoparticles, followed by coverage of single atom and molecule interactions with graphene, and finally concludes and highlights the anticipated exciting future for electron beam driving chemistry in and around graphene. Various electron–specimen processes driven by the imaging electron beam in a transmission electron microscope are shown for their exciting potential to drive a number of novel reactions in and around graphene with no other external driving mechanism. Initially, the fundamental physics is presented, and then the various types of reactions are reviewed in an informative and concise manner.