Step edge structures on the anatase TiO2 (001) surface studied by atomic-resolution TEM and STM

Low-coordinate surface sites, such as those present on high-index step edges, often exhibit chemical reactivity that markedly differs from more close-packed facets. To understand the site-specific reactivity, insight into the three-dimensional atomic arrangement of step edges is needed. Here, we emp...

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Veröffentlicht in:Faraday discussions 2018, Vol.208, p.325-338
Hauptverfasser: M Ek, Beinik, I, Bruix, A, Wendt, S, Lauritsen, J V, Helveg, S
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Beinik, I
Bruix, A
Wendt, S
Lauritsen, J V
Helveg, S
description Low-coordinate surface sites, such as those present on high-index step edges, often exhibit chemical reactivity that markedly differs from more close-packed facets. To understand the site-specific reactivity, insight into the three-dimensional atomic arrangement of step edges is needed. Here, we employ atomic-resolution transmission electron microscopy (TEM) of nanoparticles in combination with scanning tunneling microscopy (STM) of a single crystal surface to uncover the structure of prevalent step edges on the anatase TiO2 (001) surface.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Anatase
Crystal structure
Crystal surfaces
Microscopes
Microscopy
Organic chemistry
Scanning tunneling microscopy
Single crystals
Titanium dioxide
Transmission electron microscopy
title Step edge structures on the anatase TiO2 (001) surface studied by atomic-resolution TEM and STM
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