Spin State Chemistry: Modulation of Ligand p Ka by Spin State Switching in a [2×2] Iron(II) Grid-Type Complex

The iron(II) [2×2] grid complex Fe-8H has been synthesized and characterized. It undergoes spin-crossover (SCO) upon deprotonation of the hydrazine-based terpyridine-like ligand. The deprotonation patterns have been determined by X-ray crystallography and 1H NMR spectroscopy and discussed in relatio...

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Veröffentlicht in:	Journal of the American Chemical Society 2018-07, Vol.140 (26), p.8218-8227
Hauptverfasser:	Dhers, Sébastien, Mondal, Abhishake, Aguilà, David, Ramírez, Juan, Vela, Sergi, Dechambenoit, Pierre, Rouzières, Mathieu, Nitschke, Jonathan R, Clérac, Rodolphe, Lehn, Jean-Marie
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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