Mixed metal double salt ionic liquids comprised of [HN222]2[ZnCl4] and AlCl3 provide tunable Lewis acid catalysts related to the ionic environment

Two solids of differing Lewis acidities, triethylammonium tetrachlorozincate ([HN222]2[ZnCl4]) and AlCl3, have been combined across 0.1 to 0.9 mole fractions (with respect to [HN222]2[ZnCl4]), and homogeneous solid double salts or mixed metal [HN222]2x[(1 − x)AlCl3 + xZnCl4] double salt ionic liquid...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (23), p.7795-7803
Hauptverfasser:	Rajkumar Kore, Kelley, Steven P, Aduri, Pavankumar, Rogers, Robin D
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Acetophenone Aluminum chloride Catalysis Catalytic activity Desorption Infrared spectroscopy Ionic liquids Ionization Ions Lewis acid Mass spectrometry Melting points NMR Nuclear magnetic resonance Single crystals Synergistic effect X-ray diffraction Zinc chloride
Online-Zugang:	Volltext
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