New Vistas in Transmetalation with Discrete “AgCF3” Species: Implications in Pd‐Mediated Trifluoromethylation Reactions

This work describes the employment of discrete “AgCF3” complexes as efficient transmetalating agents to PdII to surmount overlooked challenges related to the transmetalation step in Pd‐catalyzed trifluoromethylation processes. We report the participation of a unique silver ate (Cs)[Ag(CF3)2] complex...

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Veröffentlicht in:	Chemistry : a European journal 2018-08, Vol.24 (46), p.11895-11898
Hauptverfasser:	Martínez de Salinas, Sara, Mudarra, Ángel L., Benet‐Buchholz, Jordi, Parella, Teodor, Maseras, Feliu, Pérez‐Temprano, Mónica H.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry Organic chemistry organometallic synthesis Silver structural elucidation transmetalation trifluoromethylation
Online-Zugang:	Volltext
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