Facile Separation, Spectroscopic Identification, and Electrochemical Properties of Higher Trifluoromethylated Derivatives of [70]Fullerene

We survey the structure and electronic properties of the family of higher trifluoromethylated C70(CF3)n molecules with n=14, 16, 18, and 20. Twenty‐two available compounds, of which thirteen are newly obtained and characterized, demonstrate the broad diversity of π‐system topologies, which enabled u...

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Veröffentlicht in:	Chemistry, an Asian journal an Asian journal, 2018-08, Vol.13 (15), p.1920-1931
Hauptverfasser:	Kosaya, Maria P., Rybalchenko, Alexey V., Lukonina, Natalia S., Mazaleva, Olga N., Ioffe, Ilya N., Markov, Vitaliy Yu, Troyanov, Sergey I., Sidorov, Lev N., Tamm, Nadezhda B., Goryunkov, Alexey A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry density functional theory (DFT) Electrochemical analysis Electrolysis Electron transfer electronic structure fullerenes molecular electrochemistry Molecular orbitals Properties (attributes) Reduction (electrolytic) structure elucidation UV/Vis spectroscopy
Online-Zugang:	Volltext
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