Covalent switching, involving divinylbenzene ligands within 3D coordination polymers, indicated by changes in fluorescence

Reversible cycloaddition reactions between 1,4-bis[2-(3-pyridyl)ethenyl]benzene and its photodimers were performed within a pair of three-dimensional coordination polymers with retention of single crystal character. In each case, switching between two crystalline forms could be followed by monitorin...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2018, Vol.54 (46), p.5831-5834
Hauptverfasser: Li, Ni-Ya, Liu, Dong, Abrahams, Brendan F, Lang, Jian-Ping
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creator Li, Ni-Ya
Liu, Dong
Abrahams, Brendan F
Lang, Jian-Ping
description Reversible cycloaddition reactions between 1,4-bis[2-(3-pyridyl)ethenyl]benzene and its photodimers were performed within a pair of three-dimensional coordination polymers with retention of single crystal character. In each case, switching between two crystalline forms could be followed by monitoring the flourescence behaviour.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Benzene
Coordination polymers
Cycloaddition
Divinylbenzene
Fluorescence
Polymers
Single crystals
Switching
title Covalent switching, involving divinylbenzene ligands within 3D coordination polymers, indicated by changes in fluorescence
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