Argentophilic Interactions in Solution: An EXAFS Study of Silver(I) Nitrene Transfer Catalysts

Silver­(I) catalysts have been developed for nitrene transfer reactions such as aziridination and C–H insertion. For some catalysts, structures determined by X-ray crystallography reveal dimers with silver–silver interactions, leading to mechanistic speculation about the potential role of dinuclear...

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Veröffentlicht in:Inorganic chemistry 2018-05, Vol.57 (10), p.5720-5722
Hauptverfasser: Mak, Choi L, Bostick, Benjamin C, Yassin, Nadine M, Campbell, Michael G
Format: Artikel
Sprache:eng
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