Iron and Cobalt Diazoalkane Complexes Supported by β‑Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation

Diazoalkanes are interesting redox-active ligands and also precursors to carbene fragments. We describe a systematic study of the binding and electronic structure of diphenyldiazomethane complexes of β-diketiminate supported iron and cobalt, which span a range of formal d-electron counts of 7–9. In...

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Veröffentlicht in:	Inorganic chemistry 2018-05, Vol.57 (10), p.5959-5972
Hauptverfasser:	Bonyhady, Simon J, DeRosha, Daniel E, Vela, Javier, Vinyard, David J, Cowley, Ryan E, Mercado, Brandon Q, Brennessel, William W, Holland, Patrick L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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