Acylstannanes: Cleavable and Highly Reactive Photoinitiators for Radical Photopolymerization at Wavelengths above 500 nm with Excellent Photobleaching Behavior

Within this work, a novel acylstannane‐based photoinitiator (PI) is presented. Tetrakis(2,4,6‐trimethylbenzoyl)stannane (1) displays outstanding properties compared to state‐of‐the‐art acylgermane‐based initiators. Most importantly, the initiator shows absorption up to 550 nm, which allows higher pe...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-09, Vol.57 (37), p.12146-12150
Hauptverfasser:	Mitterbauer, Moritz, Knaack, Patrick, Naumov, Sergej, Markovic, Marica, Ovsianikov, Alexandr, Moszner, Norbert, Liska, Robert
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical bonds Cytotoxicity Initiators Organotin compounds Photobleaching Photoinitiators Photopolymerization Photopolymers Tin Toxicity visible light Wavelengths
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