Dynamic Intermediates in the Radical Cation Diels–Alder Cycloaddition: Lifetime and Suprafacial Stereoselectivity

Cation radical Diels–Alder cycloadditions proceed via an acyclic intermediate that exists on a flat region of the potential energy surface. Competition between cyclization and C–C bond rotation results in varying levels of suprafacial stereoselectivity. Quasi-classical trajectories were used to expl...

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Veröffentlicht in:	Organic letters 2018-05, Vol.20 (10), p.2821-2825
Hauptverfasser:	Tan, Jacqueline S. J, Hirvonen, Viivi, Paton, Robert S
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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