Selective Inclusion of a Hetero-Guest Pair in a Molecular Host: Formation of Stable Charge-Transfer Complexes in Cucurbit[8]uril
Two different molecules are selectively included in cucurbit[8]uril to form a stable 1:1:1 ternary complex, which has been characterized by X‐ray crystallography (see picture). The inclusion of a hetero‐guest pair (a pyridinium derivative (blue) and 2,6‐dihydroxynaphthalene (magenta)) in the molecul...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2001-04, Vol.40 (8), p.1526-1529 |
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| container_issue | 8 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Kim, Hee-Joon Heo, Jungseok Jeon, Woo Sung Lee, Eunsung Kim, Jaheon Sakamoto, Shigeru Yamaguchi, Kentaro Kim, Kimoon |
| description | Two different molecules are selectively included in cucurbit[8]uril to form a stable 1:1:1 ternary complex, which has been characterized by X‐ray crystallography (see picture). The inclusion of a hetero‐guest pair (a pyridinium derivative (blue) and 2,6‐dihydroxynaphthalene (magenta)) in the molecular host is driven and stabilized by a charge‐transfer interaction between the electron‐rich and electron‐deficient guests. |
| doi_str_mv | 10.1002/1521-3773(20010417)40:8<1526::AID-ANIE1526>3.0.CO;2-T |
| format | Article |
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Chem. Int. Ed</addtitle><date>2001-04-17</date><risdate>2001</risdate><volume>40</volume><issue>8</issue><spage>1526</spage><epage>1529</epage><pages>1526-1529</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Two different molecules are selectively included in cucurbit[8]uril to form a stable 1:1:1 ternary complex, which has been characterized by X‐ray crystallography (see picture). The inclusion of a hetero‐guest pair (a pyridinium derivative (blue) and 2,6‐dihydroxynaphthalene (magenta)) in the molecular host is driven and stabilized by a charge‐transfer interaction between the electron‐rich and electron‐deficient guests.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><pmid>29712342</pmid><doi>10.1002/1521-3773(20010417)40:8<1526::AID-ANIE1526>3.0.CO;2-T</doi><tpages>4</tpages></addata></record> |
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| source | Access via Wiley Online Library |
| subjects | charge transfer host-guest chemistry inclusion compounds structure elucidation supramolecular chemistry |
| title | Selective Inclusion of a Hetero-Guest Pair in a Molecular Host: Formation of Stable Charge-Transfer Complexes in Cucurbit[8]uril |
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