Experimental Detection of Tetraoxygen

Although suggested by Lewis in 1924 and theoretically predicted, O4 has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O4 species. The search has now been brought to an end by the conclusive proof, achieved by neutralization–re‐ionizat...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2001-11, Vol.40 (21), p.4062-4065
Hauptverfasser:	Cacace, Fulvio, de Petris, Giulia, Troiani, Anna
Format:	Artikel
Sprache:	eng
Schlagworte:	ion-molecule reactions mass spectrometry metastable compounds oxygen
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	4065
container_issue	21
container_start_page	4062
container_title	Angewandte Chemie International Edition
container_volume	40
creator	Cacace, Fulvio de Petris, Giulia Troiani, Anna
description	Although suggested by Lewis in 1924 and theoretically predicted, O4 has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O4 species. The search has now been brought to an end by the conclusive proof, achieved by neutralization–re‐ionization mass spectrometry (see picture), of the existence of intact O4 as a gas‐phase species with a lifetime in excess of 1 μs, whose dissociation requires overcoming a barrier of the order of 10 kcal mol−1.
doi_str_mv	10.1002/1521-3773(20011105)40:21<4062::AID-ANIE4062>3.0.CO;2-X
format	Article
fullrecord	<record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_proquest_miscellaneous_2033378898</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2033378898</sourcerecordid><originalsourceid>FETCH-LOGICAL-i3312-bc38680a3e7524aee91695ba193f84902c6768563050dc905bca7987788b28083</originalsourceid><addsrcrecordid>eNo9kNtOwkAQhjdGo3h4BcONCV4UZ3e6h6IxIYhIAqKJxiZeTLZ1MdVCsS0R3t42CFc7O_PPl8zH2C2HNgcQV1wK7qHW2BIAnHOQlz50BL_xQYlOpzu887qPw379u8U2tHuTa-GFe6yxW9yvah_R00byI3ZcFF8V1xhQh-xIBJoL4asGu-ivFi5PZm5e2rR550oXl0k2b2bT5osrc5ut1p9ufsoOpjYt3Nn_e8Je7_svvQdvNBkMe92RlyBy4UUxGmXAotNS-Na5gKtARpYHODV-ACJWWhmpECR8xAHIKLY6MFobEwkDBk9Ya8Nd5NnP0hUlzZIidmlq5y5bFiQAEat0UEfP_6PLaOY-aFEdYfM1bU-rAu-bwG-SuvVuzoFqwVR7otoTbQWTD1T1aqVU-aWtX0IC6k1IULjrVXRvQ0-K0q12dJt_k9KoJb09DujZH4zH4VNIIf4BJcR-3A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2033378898</pqid></control><display><type>article</type><title>Experimental Detection of Tetraoxygen</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Cacace, Fulvio ; de Petris, Giulia ; Troiani, Anna</creator><creatorcontrib>Cacace, Fulvio ; de Petris, Giulia ; Troiani, Anna</creatorcontrib><description>Although suggested by Lewis in 1924 and theoretically predicted, O4 has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O4 species. The search has now been brought to an end by the conclusive proof, achieved by neutralization–re‐ionization mass spectrometry (see picture), of the existence of intact O4 as a gas‐phase species with a lifetime in excess of 1 μs, whose dissociation requires overcoming a barrier of the order of 10 kcal mol−1.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/1521-3773(20011105)40:21<4062::AID-ANIE4062>3.0.CO;2-X</identifier><identifier>PMID: 29712246</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag GmbH</publisher><subject>ion-molecule reactions ; mass spectrometry ; metastable compounds ; oxygen</subject><ispartof>Angewandte Chemie International Edition, 2001-11, Vol.40 (21), p.4062-4065</ispartof><rights>2001 WILEY‐VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany</rights><rights>2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2F1521-3773%2820011105%2940%3A21%3C4062%3A%3AAID-ANIE4062%3E3.0.CO%3B2-X$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2F1521-3773%2820011105%2940%3A21%3C4062%3A%3AAID-ANIE4062%3E3.0.CO%3B2-X$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29712246$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cacace, Fulvio</creatorcontrib><creatorcontrib>de Petris, Giulia</creatorcontrib><creatorcontrib>Troiani, Anna</creatorcontrib><title>Experimental Detection of Tetraoxygen</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Although suggested by Lewis in 1924 and theoretically predicted, O4 has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O4 species. The search has now been brought to an end by the conclusive proof, achieved by neutralization–re‐ionization mass spectrometry (see picture), of the existence of intact O4 as a gas‐phase species with a lifetime in excess of 1 μs, whose dissociation requires overcoming a barrier of the order of 10 kcal mol−1.</description><subject>ion-molecule reactions</subject><subject>mass spectrometry</subject><subject>metastable compounds</subject><subject>oxygen</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNo9kNtOwkAQhjdGo3h4BcONCV4UZ3e6h6IxIYhIAqKJxiZeTLZ1MdVCsS0R3t42CFc7O_PPl8zH2C2HNgcQV1wK7qHW2BIAnHOQlz50BL_xQYlOpzu887qPw379u8U2tHuTa-GFe6yxW9yvah_R00byI3ZcFF8V1xhQh-xIBJoL4asGu-ivFi5PZm5e2rR550oXl0k2b2bT5osrc5ut1p9ufsoOpjYt3Nn_e8Je7_svvQdvNBkMe92RlyBy4UUxGmXAotNS-Na5gKtARpYHODV-ACJWWhmpECR8xAHIKLY6MFobEwkDBk9Ya8Nd5NnP0hUlzZIidmlq5y5bFiQAEat0UEfP_6PLaOY-aFEdYfM1bU-rAu-bwG-SuvVuzoFqwVR7otoTbQWTD1T1aqVU-aWtX0IC6k1IULjrVXRvQ0-K0q12dJt_k9KoJb09DujZH4zH4VNIIf4BJcR-3A</recordid><startdate>20011105</startdate><enddate>20011105</enddate><creator>Cacace, Fulvio</creator><creator>de Petris, Giulia</creator><creator>Troiani, Anna</creator><general>WILEY-VCH Verlag GmbH</general><general>WILEY‐VCH Verlag GmbH</general><scope>BSCLL</scope><scope>NPM</scope><scope>7X8</scope></search><sort><creationdate>20011105</creationdate><title>Experimental Detection of Tetraoxygen</title><author>Cacace, Fulvio ; de Petris, Giulia ; Troiani, Anna</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3312-bc38680a3e7524aee91695ba193f84902c6768563050dc905bca7987788b28083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>ion-molecule reactions</topic><topic>mass spectrometry</topic><topic>metastable compounds</topic><topic>oxygen</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cacace, Fulvio</creatorcontrib><creatorcontrib>de Petris, Giulia</creatorcontrib><creatorcontrib>Troiani, Anna</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cacace, Fulvio</au><au>de Petris, Giulia</au><au>Troiani, Anna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Experimental Detection of Tetraoxygen</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2001-11-05</date><risdate>2001</risdate><volume>40</volume><issue>21</issue><spage>4062</spage><epage>4065</epage><pages>4062-4065</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Although suggested by Lewis in 1924 and theoretically predicted, O4 has so far proved extremely elusive, defying all attempts at the positive experimental detection of a bound, intact O4 species. The search has now been brought to an end by the conclusive proof, achieved by neutralization–re‐ionization mass spectrometry (see picture), of the existence of intact O4 as a gas‐phase species with a lifetime in excess of 1 μs, whose dissociation requires overcoming a barrier of the order of 10 kcal mol−1.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag GmbH</pub><pmid>29712246</pmid><doi>10.1002/1521-3773(20011105)40:21<4062::AID-ANIE4062>3.0.CO;2-X</doi><tpages>4</tpages></addata></record>
fulltext	fulltext
identifier	ISSN: 1433-7851
ispartof	Angewandte Chemie International Edition, 2001-11, Vol.40 (21), p.4062-4065
issn	1433-7851 1521-3773
language	eng
recordid	cdi_proquest_miscellaneous_2033378898
source	Wiley Online Library Journals Frontfile Complete
subjects	ion-molecule reactions mass spectrometry metastable compounds oxygen
title	Experimental Detection of Tetraoxygen
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-10T06%3A57%3A31IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Experimental%20Detection%20of%20Tetraoxygen&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Cacace,%20Fulvio&rft.date=2001-11-05&rft.volume=40&rft.issue=21&rft.spage=4062&rft.epage=4065&rft.pages=4062-4065&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/1521-3773(20011105)40:21%3C4062::AID-ANIE4062%3E3.0.CO;2-X&rft_dat=%3Cproquest_pubme%3E2033378898%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2033378898&rft_id=info:pmid/29712246&rfr_iscdi=true