Structural Diversity in the Solid-State Structures of the Rubidium and Cesium Salts of 2,6-Dimesitylphenylphosphane

Structural Diversity in the Solid-State Structures of the Rubidium and Cesium Salts of 2,6-Dimesitylphenylphosphane

A coordination environment reminiscent of a paddle‐wheel is exhibited by aryl groups about one of the two cesium ions in CsP(H)Dmp (Dmp=2,6‐dimesitylphenyl; structure depicted on the right), which has now been synthesized and is found to exhibit Cs+{Cs2[P(H)Dmp]3}− contact ion pairs in the solid sta...

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Veröffentlicht in:Angewandte Chemie International Edition 1998-06, Vol.37 (10), p.1404-1407
Hauptverfasser: Rabe, Gerd W., Kheradmandan, Sohrab, Liable-Sands, Louise M., Guzei, Ilia A., Rheingold, Arnold L.
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Sprache:eng
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Alkali metals
Cesium
Phosphorus
Rubidium
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container_end_page 1407
container_issue 10
container_start_page 1404
container_title Angewandte Chemie International Edition
container_volume 37
creator Rabe, Gerd W.
Kheradmandan, Sohrab
Liable-Sands, Louise M.
Guzei, Ilia A.
Rheingold, Arnold L.
description A coordination environment reminiscent of a paddle‐wheel is exhibited by aryl groups about one of the two cesium ions in CsP(H)Dmp (Dmp=2,6‐dimesitylphenyl; structure depicted on the right), which has now been synthesized and is found to exhibit Cs+{Cs2[P(H)Dmp]3}− contact ion pairs in the solid state. In contrast, the analogous rubidium compound displays a Rb4P4 cube as the central structural motif.
doi_str_mv 10.1002/(SICI)1521-3773(19980605)37:10<1404::AID-ANIE1404>3.0.CO;2-V
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subjects Alkali metals
Cesium
Phosphorus
Rubidium
title Structural Diversity in the Solid-State Structures of the Rubidium and Cesium Salts of 2,6-Dimesitylphenylphosphane
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