Analysis of the Symmetry of Crystal Packing Forces by Methyl Proton Tunneling: A Strategy for the Unambiguous Assignment of the Magnetic Jahn - Teller Effect in Molecules

Intrinsic and extrinsic forces behind the distortion in metal atom clusters can be readily distinguished provided that the clusters are embedded in a suitable ligand environment and that the tunneling of the protons in the peripheral ligands is then analyzed by inelastic neutron scattering. For the...

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Veröffentlicht in:	Angewandte Chemie International Edition 1998-02, Vol.37 (3), p.317-320
Hauptverfasser:	Jayasooriya, Upali A., Cannon, Roderick D., Anson, Christopher E., Karu, Elisha, Saad, Ahmed K., Bourke, John P., Kearley, Gordon J., White, Ross P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carboxylato complexes Chromium Jahn - Teller distortion Neutron scattering Packing effects
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description	Intrinsic and extrinsic forces behind the distortion in metal atom clusters can be readily distinguished provided that the clusters are embedded in a suitable ligand environment and that the tunneling of the protons in the peripheral ligands is then analyzed by inelastic neutron scattering. For the [Cr3O(OOCCH3)6(H2O)3]Cl⋅6 H2O model system studied, the tunneling process is very sensitive to the local environment. Thus a tool is available to allow a better assessment of the cause of structural distortions.
doi_str_mv	10.1002/(SICI)1521-3773(19980216)37:3<317::AID-ANIE317>3.0.CO;2-H
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subjects	Carboxylato complexes Chromium Jahn - Teller distortion Neutron scattering Packing effects
title	Analysis of the Symmetry of Crystal Packing Forces by Methyl Proton Tunneling: A Strategy for the Unambiguous Assignment of the Magnetic Jahn - Teller Effect in Molecules
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