Multicomponent metal-organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction
Multicomponent metal-organic framework (MOF) derivatives have attracted strong interest in energy and environmental fields. However, most of the papers focus on single MOF derivatives; reports on multicomponent MOF derivatives and their catalytic studies are relatively few. Here, we report an easy-t...
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Veröffentlicht in: | Nanoscale 2018-01, Vol.10 (18), p.8772-8778 |
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creator | Hui, Junfeng Chu, Huimin Zhang, Wenlei Shen, Yu Chen, Wanzheng Hu, Yu Liu, Wan Gao, Cong Guo, Shaohua Xiao, Gengwu Li, Sheng Fu, Yu Fan, Daidi Zhang, Weina Huo, Fengwei |
description | Multicomponent metal-organic framework (MOF) derivatives have attracted strong interest in energy and environmental fields. However, most of the papers focus on single MOF derivatives; reports on multicomponent MOF derivatives and their catalytic studies are relatively few. Here, we report an easy-to-operate strategy to obtain multicomponent MOF derivatives by treating multicomponent MOFs under a suitable gas atmosphere and at high temperature. We used ZIF-67 as a template to introduce Zn and successfully obtained multicomponent MOFs. After carbonization, the multicomponent MOF derivatives with Co and CoO nanoparticles exhibit higher conversion of styrene (≈99%), higher selectivity (≈70%) and better stability compared to MOFs and single component MOF derivatives. |
doi_str_mv | 10.1039/c8nr01336e |
format | Article |
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However, most of the papers focus on single MOF derivatives; reports on multicomponent MOF derivatives and their catalytic studies are relatively few. Here, we report an easy-to-operate strategy to obtain multicomponent MOF derivatives by treating multicomponent MOFs under a suitable gas atmosphere and at high temperature. We used ZIF-67 as a template to introduce Zn and successfully obtained multicomponent MOFs. After carbonization, the multicomponent MOF derivatives with Co and CoO nanoparticles exhibit higher conversion of styrene (≈99%), higher selectivity (≈70%) and better stability compared to MOFs and single component MOF derivatives.</description><identifier>ISSN: 2040-3364</identifier><identifier>EISSN: 2040-3372</identifier><identifier>DOI: 10.1039/c8nr01336e</identifier><identifier>PMID: 29708562</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Carbonization ; Catalysis ; Derivatives ; Epoxidation ; Metal-organic frameworks</subject><ispartof>Nanoscale, 2018-01, Vol.10 (18), p.8772-8778</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-748168b749120f77ffcc3765df265dbf713015aa58194b03fa5ecf780a02f0523</citedby><cites>FETCH-LOGICAL-c352t-748168b749120f77ffcc3765df265dbf713015aa58194b03fa5ecf780a02f0523</cites><orcidid>0000-0002-5318-4267</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27928,27929</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29708562$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hui, Junfeng</creatorcontrib><creatorcontrib>Chu, Huimin</creatorcontrib><creatorcontrib>Zhang, Wenlei</creatorcontrib><creatorcontrib>Shen, Yu</creatorcontrib><creatorcontrib>Chen, Wanzheng</creatorcontrib><creatorcontrib>Hu, Yu</creatorcontrib><creatorcontrib>Liu, Wan</creatorcontrib><creatorcontrib>Gao, Cong</creatorcontrib><creatorcontrib>Guo, Shaohua</creatorcontrib><creatorcontrib>Xiao, Gengwu</creatorcontrib><creatorcontrib>Li, Sheng</creatorcontrib><creatorcontrib>Fu, Yu</creatorcontrib><creatorcontrib>Fan, Daidi</creatorcontrib><creatorcontrib>Zhang, Weina</creatorcontrib><creatorcontrib>Huo, Fengwei</creatorcontrib><title>Multicomponent metal-organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction</title><title>Nanoscale</title><addtitle>Nanoscale</addtitle><description>Multicomponent metal-organic framework (MOF) derivatives have attracted strong interest in energy and environmental fields. 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After carbonization, the multicomponent MOF derivatives with Co and CoO nanoparticles exhibit higher conversion of styrene (≈99%), higher selectivity (≈70%) and better stability compared to MOFs and single component MOF derivatives.</description><subject>Carbonization</subject><subject>Catalysis</subject><subject>Derivatives</subject><subject>Epoxidation</subject><subject>Metal-organic frameworks</subject><issn>2040-3364</issn><issn>2040-3372</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkV1LHDEUhoNY_Ko3_gAJeCOFqfmYSTKXsqy1YFsQez1ksydrdCYZk4zt9r7_22zXeuHNOS-ch4cDL0InlHymhLcXRvlIKOcCdtABIzWpOJds9y2Leh8dpvRAiGi54Hton7WSqEawA_T329RnZ8IwBg8-4wGy7qsQV9o7g23UA_wK8REvIbpnnd0zJGxDxGHMbnB_nF_hfA84QQ9mc8VGF8G6KPEIsZCD9gZwsDjldQQPGMbw2y2LKngcQZtN-Ig-WN0nOH7dR-jn1fxudl3d_PjydXZ5UxnesFzJWlGhFrJuKSNWSmuN4VI0S8vKWFhJOaGN1o2ibb0g3OoGjJWKaMIsaRg_Qudb7xjD0wQpd4NLBvpeewhT6hjhTLatqEVBz96hD2GKvny3oYRSrZKqUJ-2lIkhpQi2G6MbdFx3lHSbcrqZ-n77r5x5gU9fldNigOUb-r8N_gLrfIzo</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Hui, Junfeng</creator><creator>Chu, Huimin</creator><creator>Zhang, Wenlei</creator><creator>Shen, Yu</creator><creator>Chen, Wanzheng</creator><creator>Hu, Yu</creator><creator>Liu, Wan</creator><creator>Gao, Cong</creator><creator>Guo, Shaohua</creator><creator>Xiao, Gengwu</creator><creator>Li, Sheng</creator><creator>Fu, Yu</creator><creator>Fan, Daidi</creator><creator>Zhang, Weina</creator><creator>Huo, Fengwei</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-5318-4267</orcidid></search><sort><creationdate>20180101</creationdate><title>Multicomponent metal-organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction</title><author>Hui, Junfeng ; 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However, most of the papers focus on single MOF derivatives; reports on multicomponent MOF derivatives and their catalytic studies are relatively few. Here, we report an easy-to-operate strategy to obtain multicomponent MOF derivatives by treating multicomponent MOFs under a suitable gas atmosphere and at high temperature. We used ZIF-67 as a template to introduce Zn and successfully obtained multicomponent MOFs. After carbonization, the multicomponent MOF derivatives with Co and CoO nanoparticles exhibit higher conversion of styrene (≈99%), higher selectivity (≈70%) and better stability compared to MOFs and single component MOF derivatives.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>29708562</pmid><doi>10.1039/c8nr01336e</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5318-4267</orcidid></addata></record> |
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subjects | Carbonization Catalysis Derivatives Epoxidation Metal-organic frameworks |
title | Multicomponent metal-organic framework derivatives for optimizing the selective catalytic performance of styrene epoxidation reaction |
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